Coordination behaviour and two-dimensional-network formation in poly[[μ-aqua-diaqua(μ5-propane-1,3-diyldinitrilotetraacetato)dilithium(I)cobalt(II)] dihydrate]: the first example of anMII–1,3-pdta complex with a monovalent metal counter-ion

2008 ◽  
Vol 64 (6) ◽  
pp. m217-m220 ◽  
Author(s):  
Urszula Rychlewska ◽  
Beata Warżajtis ◽  
Miloš I. Djuran ◽  
Dušanka D. Radanović ◽  
Mirjana Dj. Dimitrijević ◽  
...  
Keyword(s):  
Network Formation ◽  
Two Dimensional ◽  
Monovalent Metal ◽  
Counter Ion ◽  
Dimensional Network ◽  
Coordination Behaviour

scholarly journals Harnessing by a diacetylene unit: a molecular design for porous two-dimensional network formation at the liquid/solid interface

2014 ◽  
Vol 50 (22) ◽  
pp. 2831 ◽  
Author(s):  
Kazukuni Tahara ◽  
Jinne Adisoejoso ◽  
Koji Inukai ◽  
Shengbin Lei ◽  
Aya Noguchi ◽  
...  
Keyword(s):  
Network Formation ◽  
Molecular Design ◽  
Two Dimensional ◽  
Solid Interface ◽  
Dimensional Network

Two-dimensional network formation of cardiac myocytes in agar microculture chip with 1480 nm infrared laser photo-thermal etching

Lab on a Chip ◽  
2003 ◽  
Vol 3 (4) ◽  
pp. 292 ◽  
Author(s):  
Kensuke Kojima ◽  
Hiroyuki Moriguchi ◽  
Akihiro Hattori ◽  
Tomoyuki Kaneko ◽  
Kenji Yasuda
Keyword(s):  
Cardiac Myocytes ◽  
Network Formation ◽  
Infrared Laser ◽  
Two Dimensional ◽  
Thermal Etching ◽  
Dimensional Network

Two-Dimensional Network Formation in the C60Malonic Acid Adlayer on Au(111)

2007 ◽  
Vol 111 (36) ◽  
pp. 13297-13300 ◽  
Author(s):  
Masashi Matsumoto ◽  
Junji Inukai ◽  
Soichiro Yoshimoto ◽  
Yoko Takeyama ◽  
Osamu Ito ◽  
...  
Keyword(s):  
Network Formation ◽  
Two Dimensional ◽  
Dimensional Network

scholarly journals Crystal structure of 2-nitro-N-(5-nitro-1,3-thiazol-2-yl)benzamide

2014 ◽  
Vol 70 (12) ◽  
pp. o1252-o1252 ◽  
Author(s):  
Rodolfo Moreno-Fuquen ◽  
Diego F. Sánchez ◽  
Javier Ellena
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Dihedral Angles ◽  
Two Dimensional ◽  
Compound C ◽  
Dimensional Network ◽  
Benzene Rings ◽  
The Mean ◽  
Amide Fragment

In the title compound, C10H6N4O5S, the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C [r.m.s. deviation = 0.0294 Å] forms dihedral angles of 12.48 (7) and 46.66 (9)° with the planes of the thiazole and benzene rings, respectively. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains along [001]. In addition, weak C—H...O hydrogen bonds link these chains, forming a two-dimensional network, containingR44(28) ring motifs parallel to (100).

Poly[[μ2-1,3-bis(pyridin-4-yl)propane](μ3-1,4-phenylenediacetato)cadmium]

2012 ◽  
Vol 68 (2) ◽  
pp. m34-m36 ◽  
Author(s):  
Dong Liu
Keyword(s):  
Title Complex ◽  
Point Of View ◽  
Solvothermal Reaction ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Connected Network ◽  
Dimensional Network

Solvothermal reaction between Cd(NO3)2, 1,4-phenylenediacetate (1,4-PDA) and 1,3-bis(pyridin-4-yl)propane (bpp) afforded the title complex, [Cd(C10H8O4)(C13H14N2)]n. Adjacent carboxylate-bridged CdIIions are related by an inversion centre. The 1,4-PDA ligands adopt acisconformation and connect the CdIIions to form a one-dimensional chain extending along thecaxis. These chains are in turn linked into a two-dimensional network through bpp bridges. The bpp ligands adopt ananti–gaucheconformation. From a topological point of view, each bpp ligand and each pair of 1,4-PDA ligands can be considered as linkers, while the dinuclear CdIIunit can be regarded as a 6-connecting node. Thus, the structure can be simplified to a two-dimensional 6-connected network.

scholarly journals 6-Amino-3-methyl-4-(3,4,5-trimethoxyphenyl)-2,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile

2014 ◽  
Vol 70 (8) ◽  
pp. o875-o876 ◽  
Author(s):  
Naresh Sharma ◽  
Goutam Brahmachari ◽  
Bubun Banerjee ◽  
Rajni Kant ◽  
Vivek K. Gupta
Keyword(s):  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Title Compound ◽  
Pyrazole Ring ◽  
Ring System ◽  
Boat Conformation ◽  
Two Dimensional ◽  
Compound C ◽  
Dimensional Network ◽  
Centroid Distance

In the title compound, C17H18N4O4, the dihedral angle between the benzene ring and 2,4-dihydropyrano[2,3-c]pyrazole ring system is 89.41 (7)°. The pyran moiety adopts a strongly flattened boat conformation. In the crystal, molecules are linked by N—H...N, N—H...O, C—H...N and C—H...O hydrogen bonds into an infinite two-dimensional network parallel to (110). There are π–π interactions between the pyrazole rings in neighbouring layers [centroid–centroid distance = 3.621 (1) Å].

Metal-Betaine Interactions.XIV. Silver(I) 3-Carboxylato-1-pyridinioacetate Monohydrate, [Ag{C5H4(COO)NCH2.COO}]n.nH2O

1991 ◽  
Vol 44 (12) ◽  
pp. 1783 ◽  
Author(s):  
XM Chen ◽  
TCW Mak
Keyword(s):  
Oxygen Atom ◽  
Water Molecule ◽  
Lattice Water Molecule ◽  
Membered Ring ◽  
Zigzag Chain ◽  
Two Dimensional ◽  
Metal Centre ◽  
Lattice Water ◽  
Dimensional Network ◽  
Tetrahedral Environment

The complex silver(I) 3-carboxylato-1-pyridinioacetate monohydrate, [Ag{C5H4(COO)NCH2.COO}]n.nH2O, crystallizes in space group P21/c (No. 14), with Z-4, a 12.233(6), b 5.049(1), c 14.418(7)Ǻ, and β 94.96(4)°; the structure was refined to RF -0.057 for 1721 observed [I ≥ 3σ(I)] Mo Kα data. The silver(I) atom is coordinated by four carboxylato oxygen atoms in a distorted tetrahedral environment [Ag-O 2.284(5)-2.570(5)Ǻ]. The tridentate acetato group bridges the Ag1 atoms into a zigzag chain featuring an uncommon [Ag2( carboxylato -O,O′)(carboxylato-μ-1,1-O)] six- membered ring, and the coordination sphere about each metal centre is completed by the unidentate aromatic carboxylato group, resulting in a two-dimensional network in the solid. The lattice water molecule forms hydrogen bonds with the uncoordinated oxygen atom of the aromatic carboxylato group [2.755(9)Ǻ] and the coordinated oxygen atom of the acetato group [2.936(9)Ǻ].

scholarly journals 2-Amino-3-carboxypyridinium perchlorate

2012 ◽  
Vol 68 (6) ◽  
pp. o1601-o1602 ◽  
Author(s):  
Fadila Berrah ◽  
Sofiane Bouacida ◽  
Hayet Anana ◽  
Thierry Roisnel
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

The asymmetric unit includes two crystallographically independent equivalents of the title salt, C6H7N2O2 +·ClO4 −. The cations and anions form separate layers alternating along the c axis, which are linked by N—H...O, O—H...O and C—H...O hydrogen bonds into a two-dimensional network parallel to (100). Further C—H...O contacts connect these layers, forming a three-dimensional network, in which R 4 4(20) rings and C 2 2(11) infinite chains can be identified.

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