Diacetato[2,6-bis(2-pyridylamino)pyridine]nickel(II)
2006 ◽
Vol 62
(4)
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pp. m878-m880
Keyword(s):
The Ni atom in the title complex, [Ni(C2H3O2)2(C15H13N5)] or [Ni(CH3COO)2(tpdaH2)] (tpdaH2 is tripyridyldiamine), has a distorted octahedral coordination geometry formed by the tridentate tpdaH2 ligand and two acetate groups. The tpdaH2 ligand is mer-coordinated, with the N atom of the central pyridine ring in the equatorial position and the N atoms of the peripheral pyridine rings in the axial positions. The remaining three equatorial positions are occupied by the O atoms of two acetate anions. The H atoms of both NH groups of the tpdaH2 ligand are involved in strong hydrogen bonds with O atoms of adjacent complex molecules to form a three-dimensional network.
2013 ◽
Vol 69
(12)
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pp. m645-m646
2015 ◽
Vol 71
(9)
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pp. m162-m163
2016 ◽
Vol 72
(4)
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pp. 486-488
2013 ◽
Vol 69
(2)
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pp. m101-m101
2013 ◽
Vol 69
(2)
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pp. m75-m76
2012 ◽
Vol 68
(6)
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pp. m777-m778
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2013 ◽
Vol 69
(2)
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pp. m105-m105
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2012 ◽
Vol 68
(8)
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pp. m1071-m1071
2007 ◽
Vol 63
(3)
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pp. m845-m846
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2015 ◽
Vol 71
(3)
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pp. 321-323
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