scholarly journals Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) dichloride dihydrate

2012 ◽  
Vol 68 (6) ◽  
pp. m777-m778 ◽  
Author(s):  
Ying Wang ◽  
Rui Jiao ◽  
Xiang-Lei Qiu ◽  
Jian Wang ◽  
Wei Huang
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Maximum Deviation ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Terpyridine Ligands

In the cation of the title compound, [Ru(C15H10ClN3)2]Cl2·2H2O, the metal atom exhibits a distorted octahedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water molecules are linked into a three-dimensional network by C—H...Cl, C—H...O and O—H...Cl hydrogen bonds.

scholarly journals Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate

2015 ◽  
Vol 71 (9) ◽  
pp. m162-m163
Author(s):  
Siddhartha S. Baisya ◽  
Baidyanath Ghosh ◽  
Parag S. Roy
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Carboxylate Ligand ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the title compound, [Zn(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate ligand, a bidentate ancillary 1,10-phenanthroline (phen) ligand and a water molecule complete a distorted octahedral coordination geometry around the ZnIIatom. The pterin ligand forms two chelate rings. The phen and pterin ring systems are nearly perpendicular [dihedral angle = 85.16 (5)°]. Classical N—H...O, O—H...N and O—H...O hydrogen bonds and weak C—H...O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. π–π stacking contacts are observed as well, with centroid-to-centroid distances of 3.5679 (14), 3.7004 (14), 3.6641 (15), 3.6974 (13) and 3.3412 (12) Å.

scholarly journals Crystal structure of bis{μ2-3-(pyridin-2-yl)-5-[(1,2,4-triazol-1-yl)methyl]-1,2,4-triazolato}bis[aquanitratocopper(II)] dihydrate

2016 ◽  
Vol 72 (4) ◽  
pp. 486-488
Author(s):  
Roman Doroschuk
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Coordination Geometry ◽  
Π Interactions ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The structure of the dinuclear title complex, [Cu2(C10H8N7)2(NO3)2(H2O)2]·2H2O, consists of centrosymmetric dimeric units with a copper–copper separation of 4.0408 (3) Å. The CuIIions in the dimer display a distorted octahedral coordination geometry and are bridged by two triazole rings, forming an approximately planar Cu2N4core (r.m.s. deviation = 0.049 Å). In the crystal, O—H...O, O—H...N and C—H...O hydrogen bonds and π–π interactions link the molecules into a three-dimensional network.

scholarly journals catena-Poly[[diaquabis(1H-imidazole-κN3)cobalt(II)]-μ-2,3,5,6-tetrachloroterephthalato-κ2O1:O4]

2012 ◽  
Vol 68 (4) ◽  
pp. m368-m368
Author(s):  
Chang-Ge Zheng ◽  
Peng Zhang ◽  
Ping Li ◽  
Pei-Pei Zhang
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
A Chain

In the title compound, [Co(C8Cl4O4)(C3H4N2)2(H2O)2]n, the CoIIion displays a distorted octahedral coordination geometry with two O atoms from two monodentate tetrachloroterephthalate dianions, two N atoms from two imidazole molecules and two O atoms from two water molecules. The CoIIions are connectedviathe tetrachloroterephthalate dianions into a chain running along the crystallographic [110] direction. Adjacent chains are linked into a two-dimensional network arranged parallel to (010) by classical N—H...O and O—H...O hydrogen bonds.

scholarly journals Bis(5-amino-1H-tetrazole-κN4)diaqua(oxalato-κ2O1,O2)cadmium

2013 ◽  
Vol 69 (12) ◽  
pp. m645-m646
Author(s):  
Qian Liang ◽  
Yulin Wang ◽  
Yan Zhao ◽  
Gaojuan Cao
Keyword(s):  
Three Dimensional ◽  
Title Complex ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Oxalate Ligand ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the monomeric title complex, [Cd(C2O4)(CH3N5)2(H2O)2], the CdIIion exhibits a distorted octahedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino-1H-tetrazole ligands; the axial sites are occupied by two water molecules, with longer Cd—O bond lengths. An intramolecular N—H...O hydrogen bond occurs. In the crystal, N—H...O as well as O—H...O and O—H...N hydrogen bonds (some of which are bifurcated) link the complex molecules into a three-dimensional network.

scholarly journals Poly[[aqua(μ2-4,4′-bipyridine-κ2N:N′)[μ3-3-bromo-2-(carboxylatomethyl)benzoato-κ3O1:O1′:O2]cadmium] monohydrate]

2012 ◽  
Vol 68 (8) ◽  
pp. m1071-m1071
Author(s):  
Yangmei Liu ◽  
Kai Cao ◽  
Fenglin Wang
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Three Dimensional ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Centroid Distance ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Benzene Rings

In the title compound, {[Cd(C9H5BrO4)(C10H8N2)(H2O)]·H2O}n, the CdIIatom has a distorted octahedral coordination geometry. Two N atoms from two 4,4′-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxylate O atoms from three 3-bromo-2-(carboxylatomethyl)benzoate (bcb) ligands and one O atom from a water molecule. The bipy and bcb ligands link the CdIIatoms into a three-dimensional network. O—H...O hydrogen bonds and π–π interactions between the pyridine and benzene rings [centroid–centroid distance = 3.736 (4) Å] are present in the crystal.

scholarly journals Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)copper(II) trihydrate

2014 ◽  
Vol 70 (11) ◽  
pp. 348-351 ◽  
Author(s):  
Siddhartha S. Baisya ◽  
Parag S. Roy
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Ring System ◽  
Maximum Deviation ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Aromatic Rings ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the title compound, [Cu(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, the CuIIcation isO,N,O′-chelated by the 2-amino-7-methyl-4-oxidopteridine-6-carboxylate anion andN,N′-chelated by the 1,10-phenanthroline (phen) ligand. A water molecule further coordinates to the CuIIcation to complete the elongated distorted octahedral coordination geometry. In the molecule, the pteridine ring system is essentially planar [maximum deviation = 0.055 (4) Å], and its mean plane is nearly perpendicular to the phen ring system [dihedral angle = 85.97 (3)°]. In the crystal, N—H...O, O—H...N and O—H...·O hydrogen bonds, as well as weak C—H...O hydrogen bonds and C—H...π interactions, link the complex molecules and lattice water molecules into a three-dimensional supramolecular architecture. Extensive π–π stacking between nearly parallel aromatic rings of adjacent molecules are also observed, the centroid-to-centroid distances being 3.352 (2), 3.546 (3), 3.706 (3) and 3.744 (3) Å.

scholarly journals Bis[μ-4-(4-carboxyphenoxy)phthalato]bis[triaquacobalt(II)]

2013 ◽  
Vol 69 (2) ◽  
pp. m101-m101
Author(s):  
Liang Wang
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Coordination Geometry ◽  
Carboxylate Group ◽  
Inversion Center ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The dinuclear title complex, [Co2(C15H8O7)2(H2O)6], lies across an inversion center. The unique CoIIion is coordinated in a slightly distorted octahedral coordination geometry by two O atoms from a chelating 4-(carboxyphenoxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxylate group of a symmetry-related 4-(carboxyphenoxy)phthalate ligand. In the crystal, O—H...O hydrogen bonds link the molecules into a three-dimensional network.

scholarly journals Crystal structure ofcatena-poly[[diaquabis(4-formylbenzoato-κO1)cobalt(II)]-μ-pyrazine-κ2N:N′]

2015 ◽  
Vol 71 (4) ◽  
pp. 339-341 ◽  
Author(s):  
Gülçin Şefiye Aşkın ◽  
Fatih Çelik ◽  
Nefise Dilek ◽  
Hacali Necefoğlu ◽  
Tuncer Hökelek
Keyword(s):  
Hydrogen Bonds ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Water Molecules ◽  
Carboxylate Group ◽  
Polymeric Compound ◽  
Distorted Octahedral Coordination ◽  
Linear Chains ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title polymeric compound, [Co(C8H5O3)2(C4H4N2)(H2O)2]n, the CoIIatom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of two bridging pyrazine ligands. The latter are bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 7.50 (8)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 64.90 (4)°. The pyrazine ligands bridge the CoIIcations, forming linear chains running along theb-axis direction. Strong intramolecular O—H...O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, weak O—Hwater...Owaterhydrogen bonds link adjacent chains into layers parallel to thebcplane. The layers are linkedviaC—Hpyrazine...Oformylhydrogen bonds, forming a three-dimensional network. There are also weak C—H...π interactions present.

Diacetato[2,6-bis(2-pyridylamino)pyridine]nickel(II)

2006 ◽  
Vol 62 (4) ◽  
pp. m878-m880
Author(s):  
Yin-Qiu Liu ◽  
Xi-Rui Zeng ◽  
Han-Mao Kuang ◽  
Hua-Long Chen ◽  
Qiu-Yan Luo
Keyword(s):  
Pyridine Ring ◽  
Three Dimensional ◽  
Title Complex ◽  
Equatorial Position ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The Ni atom in the title complex, [Ni(C2H3O2)2(C15H13N5)] or [Ni(CH3COO)2(tpdaH2)] (tpdaH2 is tripyridyldiamine), has a distorted octahedral coordination geometry formed by the tridentate tpdaH2 ligand and two acetate groups. The tpdaH2 ligand is mer-coordinated, with the N atom of the central pyridine ring in the equatorial position and the N atoms of the peripheral pyridine rings in the axial positions. The remaining three equatorial positions are occupied by the O atoms of two acetate anions. The H atoms of both NH groups of the tpdaH2 ligand are involved in strong hydrogen bonds with O atoms of adjacent complex molecules to form a three-dimensional network.

scholarly journals Diaquabis[4-(dimethylamino)pyridine-κN 1]bis[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)acetato-κO 1]cobalt(II)

IUCrData ◽  
2019 ◽  
Vol 4 (1) ◽  
Author(s):  
Naouel Makouf ◽  
Aziza Chouiter ◽  
Henia Bouzidi Mousser ◽  
Amel Djedouani ◽  
Solenne Fleutot ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Supramolecular Structure ◽  
Title Complex ◽  
Water Molecules ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Coordination Water

In the mononuclear title complex, [Co(C10H6NO4)2(C7H10N2)2(H2O)2], the CoII ion is located on an inversion centre and has a distorted octahedral coordination geometry of type CoN2O4 by two N atoms from the two 4-(dimethylamino)pyridine (DMAP) ligands, two carboxylate O atoms from the two deprotonated N-phthaloylglycine (Nphgly) ligands [systematic name: 2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)acetate] and two coordination water molecules. In the crystal, O—H...O, C—H...O hydrogen bonds and π–π stacking interactions link the molecules into the supramolecular structure.

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