Di-μ2-methanolato-bis[tetrakis(pyrimidin-2-amine-κN
1)cobalt(II)] bis(tetrafluoroborate)
2006 ◽
Vol 62
(5)
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pp. m1159-m1161
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Keyword(s):
The title compound, [Co2(CH3O)2(C4H5N3)4](BF4)2, consists of a discrete dimeric CoII complex. The asymmetric unit consists of one pyrimidin-2-amine ligand, which occupies a general position, and one methanolate group, as well as one CoII cation and one tetrafluoroborate anion, which are located in special positions. The CoII cation lies on a twofold rotation axis, whereas the tetrafluoroborate anion and the methanolate group lie on mirror planes. The N atoms of the pyrimidin-2-amine ligand are involved in intermolecular hydrogen bonding. From this arrangement, large channels are formed, which elongate in the direction of the crystallographic c axis.
2022 ◽
Vol 78
(1)
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2012 ◽
Vol 68
(6)
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pp. o1801-o1801
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2012 ◽
Vol 68
(8)
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pp. m1040-m1040
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Keyword(s):
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2014 ◽
Vol 70
(12)
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pp. m401-m402
Keyword(s):
2017 ◽
Vol 73
(2)
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pp. 183-187
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2015 ◽
Vol 71
(12)
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pp. 1436-1438
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2018 ◽
Vol 74
(3)
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pp. 287-291
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2006 ◽
Vol 62
(7)
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pp. o2765-o2767
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2006 ◽
Vol 62
(4)
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pp. o1319-o1320
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