[Tris(2-aminoethyl)amine-κ3 N,N′,N′′,N′′′](L-tyrosinato-κ2 N,O)nickel(II) iodide dihydrate

2006 ◽  
Vol 62 (7) ◽  
pp. m1668-m1670 ◽  
Author(s):  
Yamei Pei ◽  
Li Wang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Ni(C9H10NO3)(C6H18N4)]I·2H2O, the NiII atom is in a slightly distorted octahedral coordination environment. In the crystal structure, extensive hydrogen bonding links molecules into a three-dimensional network.

scholarly journals Bis{N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycinato-κ3O,N,O′}iron(II)

2014 ◽  
Vol 70 (7) ◽  
pp. m274-m274
Author(s):  
Ning Jiang ◽  
Juan-Juan Hou
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Inversion Center ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Fe(C6H12NO5)2], the FeIIion lies on an inversion center and is coordinated by two N atoms and four O atoms from two tridentateN-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycine ligands, forming a slightly distorted octahedral coordination environment. In the crystal, O—H...O, O—H...N and weak C—H...O hydrogen bonds link molecules, forming a three-dimensional network.

scholarly journals Bis(1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane)tetraisothiocyanatocobalt(II)

IUCrData ◽  
2020 ◽  
Vol 5 (1) ◽  
Author(s):  
Niels Ole Giltzau ◽  
Martin Köckerling
Keyword(s):  
Hydrogen Bonding ◽  
Equatorial Plane ◽  
Title Compound ◽  
Unit Cell ◽  
Octahedral Coordination ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Triclinic Unit Cell ◽  
Distorted Octahedral Coordination Environment

The title compound, [Co(C18H37N2)2(NCS)4], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane (DABCO+) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octahedral coordination environment of the CoII ion is completed through four N atoms of isothiocyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H...N and C—H...S between the filamentous molecules lead to the formation of layers parallel to (001).

scholarly journals Crystal structure of 4-(dimethylamino)pyridiniumcis-diaquabis(oxalato-κ2O,O′)ferrate(III) hemihydrate

2015 ◽  
Vol 71 (8) ◽  
pp. 934-936 ◽  
Author(s):  
Edith Dimitri Djomo ◽  
Frédéric Capet ◽  
Justin Nenwa ◽  
Michel M. Bélombé ◽  
Michel Foulon
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Bond Length ◽  
Three Dimensional ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Ionic Components ◽  
Distorted Octahedral Coordination Environment

The FeIIIions in the hybrid title salt, (C7H11N2)[Fe(C2O4)2(H2O)2]·0.5H2O, show a distorted octahedral coordination environment, with four O atoms from two chelating oxalate dianions and two O atoms from twocisaqua ligands. The average Fe—O(oxalate) bond length [2.00 (2) Å] is shorter than the average Fe—O(water) bond length [2.027 (19) Å]. The ionic components are connectedviaintermolecular N—H...O and O—H...O hydrogen bonds into a three-dimensional network.

scholarly journals Crystal structure offac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ2C1,N]bis[2-(pyridin-2-yl)phenyl-κ2C1,N]iridium(III)

2016 ◽  
Vol 72 (12) ◽  
pp. 1768-1770 ◽  
Author(s):  
Chi-Heon Lee ◽  
Suk-Hee Moon ◽  
Ki-Min Park ◽  
Youngjin Kang
Keyword(s):  
Crystal Structure ◽  
Equatorial Plane ◽  
Three Dimensional ◽  
Stacking Interactions ◽  
Chelating Ligands ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Ir(C11H8N)2(C18H14N)], the IrIIIion adopts a distorted octahedral coordination environment defined by threeC,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIIIion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, intermolecular π–π stacking interactions, as well as intermolecular C—H...π interactions, are present, leading to a three-dimensional network.

scholarly journals Crystal structure ofcatena-poly[[[diaquacobalt(II)]-bis(μ-hex-3-enedinitrile-κ2N:N′)] bis(tetrafluoridoborate)]

2015 ◽  
Vol 71 (6) ◽  
pp. m135-m136
Author(s):  
Jung-Su Son ◽  
Sung-Chul Lim ◽  
Hochun Lee ◽  
Seung-Tae Hong
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Three Dimensional ◽  
Water Molecules ◽  
Counter Anion ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the structure of the title salt, [Co(C6H6N2)2(H2O)2](BF4)2, the CoIIatom is located on an inversion centre. The transition metal is in a slightly distorted octahedral coordination environment, defined by the cyano N atoms of four hex-3-enedinitrile ligands in equatorial positions and the O atoms of two water molecules in axial positions. The bridging mode of the hex-3-enedinitrile ligands leads to the formation of cationic chains extending parallel to [1-10]. The BF4−counter-anion is disordered over two sets of sites [occupancy ratio = 0.512 (19):0.489 (19)]. It is located in the voids between the cationic chains and is connected to the aqua ligands of the latter through O—H...F hydrogen bonds. One methylene H atom of the hex-3-enedinitrile ligand forms another and weak C—H...O hydrogen bond with a water O atom of a neighbouring chain, thus consolidating the three-dimensional network structure.

scholarly journals Crystal structure of aqua[N-(2-oxidobenzyl-κO)-L-leucinato-κ2N,O](1,10-phenanthroline-κ2N,N′)nickel(II) pentahydrate

2015 ◽  
Vol 71 (2) ◽  
pp. 195-198 ◽  
Author(s):  
Md. Serajul Haque Faizi ◽  
Natalia O. Sharkina
Keyword(s):  
Crystal Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Complex Molecules ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Phenanthroline Ligand ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the NiIIatom is in a distorted octahedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hydroxybenzyl)amino]-4-methylpentanoic acid (HAMA) ligand and one water molecule. The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio. In the crystal, the complex molecules and solvate water molecules are associatedviaO—H...O hydrogen bonds into a three-dimensional network.

scholarly journals Crystal structure ofcatena-poly[[bis(acetato-κO)copper(II)]-bis[μ-4-(1H-imidazol-1-yl)phenol]-κ2N3:O;κ2O:N3]

2017 ◽  
Vol 73 (2) ◽  
pp. 209-212
Author(s):  
Mehmet Poyraz ◽  
Musa Sarı
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Stacking Interactions ◽  
Coordination Environment ◽  
Heterocyclic Ligand ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Cu(CH3COO)2(C9H8N2O)2]n, the CuIIion resides on a centre of inversion, displaying a tetragonally distorted octahedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated with a very long Cu...O interactions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to [100]. In the crystal, the chains are arranged in a distorted hexagonal rod packing and are linkedviaC—H...O hydrogen bonds and by π–π stacking interactions involving centrosymmetrically related pairs of imidazole and phenol rings.

scholarly journals Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-κ2N,O}(1,10-phenanthroline-κ2N,N′)nickel(II)

2017 ◽  
Vol 73 (9) ◽  
pp. 1393-1397 ◽  
Author(s):  
Md. Serajul Haque Faizi ◽  
Necmi Dege ◽  
Sergey Malinkin
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Complex Molecules ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Phenanthroline Ligand ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Ni(C13H18NO3)2(C12H8N2)], the NiIIcation shows a distorted octahedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hydroxybenzyl)amino]-4-methylpentanoate ligands. Complex molecules are connected into layers propagating along theabplaneviahydrogen bonds formed by O atoms of carboxylate and phenoxide groups, which are further connected into a three-dimensional motif.

scholarly journals Crystal structure of tetraaquabis(1,3-dimethyl-2,6-dioxo-7H-purin-7-ido-κN7)cobalt(II)

2017 ◽  
Vol 73 (9) ◽  
pp. 1302-1304 ◽  
Author(s):  
Hicham El Hamdani ◽  
Mohammed El Amane ◽  
Carine Duhayon
Keyword(s):  
Crystal Structure ◽  
Three Dimensional ◽  
Title Complex ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Intramolecular Hydrogen ◽  
Distorted Octahedral Coordination Environment

The title complex, [Co(C7H7N4O2)2(H2O)4], comprises mononuclear molecules consisting of a CoIIion, two deprotonated theophylline ligands (systematic name: 1,3-dimethyl-7H-purine-2,6-dione) and four coordinating water molecules. The CoIIatom lies on an inversion centre and has a slightly distorted octahedral coordination environment, with two N atoms of twotrans-oriented theophylline ligands and the O atoms of four water molecules. An intramolecular hydrogen bond stabilizes this conformation. A three-dimensional supramolecular network structure is formed by intermolecular O—H...O and O—H...N hydrogen bonds.

Redetermination of trans-diaquabis(picolinato-κ2 N,O)cobalt(II) dihydrate

2006 ◽  
Vol 62 (4) ◽  
pp. m796-m798 ◽  
Author(s):  
Zerrin Heren ◽  
Cem Cüneyt Ersanlı ◽  
Cem Keser ◽  
Nazan Ocak Ískeleli
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Inversion Center ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral

The crystal structure of the title compound, [Co(C6H4NO2)2(H2O)2]·2H2O, has been reinvestigated with improved precision [previous reports: Chang et al. (1972). J. Coord. Chem. 2, 31–34; Lumme et al. (1969). Suom. Kemistil. B, 42, 270]. In the title compound, the Co atom is located on an inversion center and its coordination can be described as slightly distorted octahedral, equatorially trans-coordinated by two N and O atoms of two picolinate ligands and axially coordinated by two O atoms of the water molecules. Intermolecular O—H...O and C—H...O hydrogen-bonding interactions result in the formation of an intricate three-dimensional network.

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