Bis(1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane)tetraisothiocyanatocobalt(II)
Keyword(s):
The title compound, [Co(C18H37N2)2(NCS)4], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane (DABCO+) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octahedral coordination environment of the CoII ion is completed through four N atoms of isothiocyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H...N and C—H...S between the filamentous molecules lead to the formation of layers parallel to (001).
2006 ◽
Vol 62
(7)
◽
pp. m1668-m1670
◽
2012 ◽
Vol 68
(8)
◽
pp. m1121-m1121
◽
2017 ◽
Vol 73
(2)
◽
pp. 209-212
2014 ◽
Vol 70
(7)
◽
pp. m274-m274
2007 ◽
Vol 63
(11)
◽
pp. m2676-m2677
◽
2017 ◽
Vol 73
(9)
◽
pp. 1279-1281
◽