catena-Poly[[dichloridodimethyltin(IV)]-μ-5-methylpyrazine-2-carboxylato-κ3 O:O′,N-[dimethyltin(IV)]]-μ-5-methylpyrazine-2-carboxylato-κ3 O,N:O′]

2007 ◽  
Vol 63 (3) ◽  
pp. m847-m849
Author(s):  
Jun-Ying Li ◽  
Tian-Duo Li
Keyword(s):  
Title Compound ◽  
The Other ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Carboxylate Groups ◽  
Coordination Behaviour ◽  
Distorted Trigonal Bipyramidal

The title compound, [Sn2Cl2(CH3)4(C6H5N2O2)2], forms infinite one-dimensional zigzag chains that propagate in a helical fashion along the c axis via an Sn—O=C—O—Sn—O bridge which involves the carboxylate groups of two methylpyrazinecarboxylate ligands. These display both chelating and bridging coordination behaviour. The asymmetric unit contains two Sn atoms; one adopts a distorted trigonal–bipyramidal geometry, while the other is in a distorted pentagonal–bipyramidal configuration.

(2,2′-Bipyridine-κ2 N,N′)dichlorido(dimethyl sulfoxide-κO)zinc(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2645-m2645 ◽  
Author(s):  
Katayoun Marjani ◽  
Mohsen Mousavi ◽  
Hamid Reza Khavasi ◽  
Maryam Ansari ◽  
Hamid Reza Qumi
Keyword(s):  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
The Other ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Cl Atom ◽  
Distorted Trigonal Bipyramidal

In the title compound, [ZnCl2(C10H8N2)(C2H6OS)], the Zn atom is five-coordinate, forming a distorted trigonal–bipyramidal geometry involving one Cl atom, one dimethyl sulfoxide O atom and one 2,2′-bipyridine N atom in equatorial positions, with distances Zn—Cl = 2.2863 (7) Å, Zn—O = 2.1024 (15) Å and Zn—N = 2.1546 (16) Å. The axial positions are occupied by the other 2,2′-bipyridine N atom and a Cl atom, with distances N—Zn = 2.1604 (16) Å and Zn—Cl = 2.3123 (7) Å.

Poly[bis(μ-5-iodoisophthalato)(methanol)dilead(II)] exhibiting a novel centrosymmetric rhombus-shaped I4unit

2013 ◽  
Vol 69 (5) ◽  
pp. 494-497 ◽  
Author(s):  
Shao-Hua Luo
Keyword(s):  
Hydrogen Bond ◽  
Title Compound ◽  
Three Dimensional ◽  
The Other ◽  
Methanol Molecule ◽  
Dimensional Structure ◽  
Asymmetric Unit ◽  
Aromatic Rings ◽  
One Dimensional ◽  
Carboxylate Groups

The asymmetric unit of the title compound, [Pb2(C8H3IO4)2(CH4O)]n, contains two PbIIatoms, two 5-iodoisophthalate (5-IIP2−) ligands and one coordinated methanol molecule. One Pb atom is eight-coordinated, surrounded by seven carboxylate O atoms from five 5-IIP2−ligands and one O atom from the terminal methanol ligand. The other Pb atom is seven-coordinated in a hemidirected geometry, surrounded by seven carboxylate O atoms from five 5-IIP2−ligands. Both Pb atoms are connected by carboxylate groups to form a one-dimensional infinite rod along theaaxis; neighbouring rods are further linked by the aromatic rings of 5-IIP2−to generate the final three-dimensional structure with channels in theadirection. An O—H...O hydrogen bond between the methanol ligand and one of the carboxylate groups of a 5-IIP2−ligand stablizes the three-dimensional framework. Interestingly, a centrosymmetric rhombus-shaped I4unit is formed by four 5-IIP2−ligands, with I...I distances of 3.8841 (8) and 3.9204 (8) Å.

scholarly journals Crystal structure of [tris(pyridin-2-ylmethyl)amine-κ4N]copper(II) bromide

2016 ◽  
Vol 72 (6) ◽  
pp. 801-804 ◽  
Author(s):  
Emma C. Bridgman ◽  
Megan M. Doherty ◽  
Kaleigh A. Ellis ◽  
Elizabeth A. Homer ◽  
Taylor N. Lashbrook ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Outer Sphere ◽  
Asymmetric Unit ◽  
Positional Disorder ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Counter Ion ◽  
Amine Ligand ◽  
Distorted Trigonal Bipyramidal

In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuIIion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal–bipyramidal geometry.

scholarly journals catena-Poly[[trimethyltin(IV)]-μ-methylphenylphosphinato-κ2O:O′]

IUCrData ◽  
2017 ◽  
Vol 2 (10) ◽  
Author(s):  
Chunhua Fu ◽  
Rufen Zhang ◽  
Shaoliang Zhang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Title Compound ◽  
Sodium Ethoxide ◽  
Chain Structure ◽  
Polymeric Chain ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Trimethyltin Chloride ◽  
Distorted Trigonal Bipyramidal

A new trimethyltin(IV) coordination polymer, [Sn(CH3)3(C7H8O2P)], has been prepared by treatment of methylphenylphosphinic acid and trimethyltin chloride with sodium ethoxide in methanol. In the solid state, the title compound adopts an infinite one-dimensional polymeric chain structure with each SnIVatom adopting a distorted trigonal–bipyramidal geometry.

scholarly journals Di-μ-aqua-bis{diaqua[μ-4-({4-[bis(2-hydroxyethyl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)benzenesulfonato]sodium(I)}

2012 ◽  
Vol 68 (6) ◽  
pp. m847-m848
Author(s):  
Mei Zhang ◽  
Fu-Yu Sun ◽  
Gui-Zhe Zhao ◽  
Ya-Qing Liu
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

In the dinuclear title compound, [Na2(C13H15ClN5O5S)2(H2O)6] n , two Na+ cations, disposed about a centre of inversion, are linked by two bridging water molecules. The coordination geometry is based on an O5 donor set defined by four water molecules and a 4-aminobenzenesulfonate O atom in a distorted trigonal–bipyramidal geometry. In the crystal, significant O—H...O, O—H...N and N—H...O hydrogen bonds lead to the formation of a three-dimensional architecture.

scholarly journals Synthesis and crystal structure of bis(μ-2-methylbenzenethiolato-κ2S:S)bis[methyl(2-methylbenzenethiolato-κS)indium(III)]

2017 ◽  
Vol 73 (4) ◽  
pp. 481-483
Author(s):  
Glen G. Briand ◽  
Andreas Decken ◽  
Courtney M. Dickie ◽  
Gregory MacNeil
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Synthesis And Crystal Structure ◽  
Polymeric Structure ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Ring Core ◽  
Distorted Trigonal Bipyramidal

The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2ring coreviabridging (2-MeC6H4S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to theaaxisviaintermolecular In...S contacts. The In atoms are then in distorted trigonal–bipyramidal CS4bonding environments.

Poly[aqua[μ4-3,3′-(diazenediyl)dibenzoato]zinc]

2012 ◽  
Vol 69 (1) ◽  
pp. 29-32 ◽  
Author(s):  
Lei-Lei Liu ◽  
Feng Zhao
Keyword(s):  
Water Molecule ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Solvothermal Reaction ◽  
Coordination Geometry ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Carboxylate Groups ◽  
Distorted Trigonal Bipyramidal Coordination ◽  
Distorted Trigonal Bipyramidal

The solvothermal reaction of Zn(OAc)2·2H2O with 3,3′-(diazenediyl)dibenzoic acid (H2ADB) in H2O at 393 K afforded the title complex, [Zn(C14H8N2O4)(H2O)]n. The asymmetric unit contains half a ZnIIcation, half an ADB ligand and half a water molecule. Each ZnIIcentre lies on a crystallographic twofold rotation axis and is five-coordinated by four O atoms of bridging carboxylate groups from four ADB ligands and one O atom from a water molecule, forming a distorted trigonal–bipyramidal coordination geometry. The [Zn(H2O)] subunits are bridged by carboxylate groups to give one-dimensional [Zn(μ-COO)4(H2O)]nchains. The chains are linked by ADB ligands into two-dimensional sheets, and these sheets are further connected to neighbouring sheetsviahydrogen bonds (OW—HW...O), forming a three-dimensional hydrogen-bond-stabilized structure with an unprecedented 374175262topology.

scholarly journals Crystal structure ofcatena-poly[[chlorido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]-μ-chlorido]

2015 ◽  
Vol 71 (6) ◽  
pp. 624-627
Author(s):  
Rafaela Nita ◽  
Jeffrey R. Deschamps ◽  
Scott A. Trammell ◽  
D. Andrew Knight
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Bipyridine Ligand ◽  
Cl Atoms ◽  
Cl Atom ◽  
Distorted Trigonal Bipyramidal

The title compound, [CuCl2(C12H12N2)]n, was obtainedviaa DMSO-mediated dehydration of Cu(4,4′-dimethyl-2,2′-bipyridine)copper(II)·0.25H2O. The central CuIIatom is coordinated in a distorted trigonal–bipyramidal geometry by two N atoms of a chelating 4,4′-dimethyl-2,2′-bipyridine ligand [average Cu—N = 2.03 (3) Å] and three Cl atoms, one terminal with a short Cu—Cl bond of 2.2506 (10) Å, and two symmetry-equivalent and bridging bonds. The bridging Cl atom links the CuIIions into chains parallel to [001]viaone medium and one long Cu—Cl bond [2.3320 (10) and 2.5623 (9) Å]. The structure displays both inter- and intramolecular C—H...Cl hydrogen bonding.

Different ZnIIcation coordination geometries in di-μ-acetato-bis{2-chloro-6-[(pyridine-2-ylmethylimino)methyl]phenol}dizinc(II) chloroform monosolvate

2013 ◽  
Vol 69 (11) ◽  
pp. 1348-1350 ◽  
Author(s):  
Young-Inn Kim ◽  
Jin Young Lee ◽  
Young-Kwang Song ◽  
Sung Kwon Kang
Keyword(s):  
Quantum Yield ◽  
Title Compound ◽  
The Other ◽  
Bidentate Coordination ◽  
Strong Emission ◽  
Pyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Coordinate Geometry ◽  
Square Pyramidal Geometry ◽  
Distorted Trigonal Bipyramidal

In the title compound, di-μ-acetato-κ2O:O;κ2O:O′-bis[(6-chloro-2-{(E)-[(pyridin-2-yl)methylimino]methyl}phenolato-κ3N,N′,O)zinc(II)], [Zn2(C13H10ClN2O)2(C2H3O2)2]·CHCl3, the ZnIIcation adopts a five-coordinate geometry and is coordinated by two N atoms and one O atom of a tridentate 6-chloro-2-{(E)-[(pyridin-2-yl)methylimino]methyl}phenolate ligand and two O atoms of two bridging acetate groups, but their coordination geometries differ. One ZnIIcation adopts a distorted trigonal bipyramidal geometry and the other a square-pyramidal geometry. The two acetate ligands bridge two ZnIIcations with mono- and bidentate coordination modes. The title compound exhibits a strong emission at 460 nm upon excitation at 325 nm with a quantum yield of 23.1%.

scholarly journals Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ2N,N′)cadmium

2012 ◽  
Vol 68 (8) ◽  
pp. m1124-m1124 ◽  
Author(s):  
Sadif A. Shirvan ◽  
Sara Haydari Dezfuli
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Bipyridine Ligand ◽  
Distorted Trigonal Bipyramidal

In the title compound, [CdBr2(C11H10N2)(C2H6OS)], the CdIIatom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond occurs. The crystal structure is stabilized by C—H...Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å].

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