scholarly journals Synthesis and crystal structure of bis(μ-2-methylbenzenethiolato-κ2S:S)bis[methyl(2-methylbenzenethiolato-κS)indium(III)]

2017 ◽  
Vol 73 (4) ◽  
pp. 481-483
Author(s):  
Glen G. Briand ◽  
Andreas Decken ◽  
Courtney M. Dickie ◽  
Gregory MacNeil
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Synthesis And Crystal Structure ◽  
Polymeric Structure ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Ring Core ◽  
Distorted Trigonal Bipyramidal

The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2ring coreviabridging (2-MeC6H4S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to theaaxisviaintermolecular In...S contacts. The In atoms are then in distorted trigonal–bipyramidal CS4bonding environments.

scholarly journals catena-Poly[[trimethyltin(IV)]-μ-methylphenylphosphinato-κ2O:O′]

IUCrData ◽  
2017 ◽  
Vol 2 (10) ◽  
Author(s):  
Chunhua Fu ◽  
Rufen Zhang ◽  
Shaoliang Zhang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Title Compound ◽  
Sodium Ethoxide ◽  
Chain Structure ◽  
Polymeric Chain ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Trimethyltin Chloride ◽  
Distorted Trigonal Bipyramidal

A new trimethyltin(IV) coordination polymer, [Sn(CH3)3(C7H8O2P)], has been prepared by treatment of methylphenylphosphinic acid and trimethyltin chloride with sodium ethoxide in methanol. In the solid state, the title compound adopts an infinite one-dimensional polymeric chain structure with each SnIVatom adopting a distorted trigonal–bipyramidal geometry.

scholarly journals Crystal structure ofcatena-poly[[chlorido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]-μ-chlorido]

2015 ◽  
Vol 71 (6) ◽  
pp. 624-627
Author(s):  
Rafaela Nita ◽  
Jeffrey R. Deschamps ◽  
Scott A. Trammell ◽  
D. Andrew Knight
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Bipyridine Ligand ◽  
Cl Atoms ◽  
Cl Atom ◽  
Distorted Trigonal Bipyramidal

The title compound, [CuCl2(C12H12N2)]n, was obtainedviaa DMSO-mediated dehydration of Cu(4,4′-dimethyl-2,2′-bipyridine)copper(II)·0.25H2O. The central CuIIatom is coordinated in a distorted trigonal–bipyramidal geometry by two N atoms of a chelating 4,4′-dimethyl-2,2′-bipyridine ligand [average Cu—N = 2.03 (3) Å] and three Cl atoms, one terminal with a short Cu—Cl bond of 2.2506 (10) Å, and two symmetry-equivalent and bridging bonds. The bridging Cl atom links the CuIIions into chains parallel to [001]viaone medium and one long Cu—Cl bond [2.3320 (10) and 2.5623 (9) Å]. The structure displays both inter- and intramolecular C—H...Cl hydrogen bonding.

scholarly journals Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ2N,N′)cadmium

2012 ◽  
Vol 68 (8) ◽  
pp. m1124-m1124 ◽  
Author(s):  
Sadif A. Shirvan ◽  
Sara Haydari Dezfuli
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Bipyridine Ligand ◽  
Distorted Trigonal Bipyramidal

In the title compound, [CdBr2(C11H10N2)(C2H6OS)], the CdIIatom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond occurs. The crystal structure is stabilized by C—H...Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å].

Neue Oxopnictate AI3MVO4: Darstellung und Kristallstruktur von A3AsO4 (A = K, Rb, Cs) und K3BiO4 / New Oxopnictates AI3MVO4: Synthesis and Crystal Structure of A3AsO4 (A = K, Rb, Cs) and K3BiO4

2002 ◽  
Vol 57 (6) ◽  
pp. 599-604 ◽  
Author(s):  
Franziska Emmerling ◽  
Mamdouh Idilbi ◽  
Caroline Röhr
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Crystal Structures ◽  
Close Packing ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Centrosymmetric Dimers ◽  
Distorted Trigonal Bipyramidal

Abstract The title compounds have been synthesized via oxidation of the elemental pnicogenes (M = As, Bi) with the hyperoxides AO2 (A = K, Rb, Cs) and their crystal structures were determined on the basis of single crystal X-ray data. In K3AsO4 (orthorhombic, Cccm, a = 1060:1(1), b = 1135:2(1), c = 1694:0(2) pm, Z = 16) and Cs3AsO4(orthorhombic, Pnma, a = 1254:3(2), b = 902:9(2), c = 658:5(3) pm, Z = 4) isolated tetrahedra [AsO4]3- with distances As-O between 167.0 and 170.5 pm are present, which are arranged in a nearly cubic close packing. The structure of K3BiO4 (triclinic, P1̄, a = 643:18(6), b = 657:27(6), c = 762:41(7) pm, α = 101:724(2)°, β = 96:472(2)°, γ = 105:465(2)°, Z = 2) contains centrosymmetric dimers [O3BiO2BiO3]6-, in which the Bi(V) atoms are surrounded by five O atoms in a distorted trigonal bipyramidal geometry with distances Bi-O in the range of 199.5 to 233.1 pm.

scholarly journals Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ2 N′,O}cadmium

2012 ◽  
Vol 68 (6) ◽  
pp. m842-m842 ◽  
Author(s):  
Mehmet Akkurt ◽  
Ali Akbar Khandar ◽  
Muhammad Nawaz Tahir ◽  
Seyed Abolfazl Hosseini Yazdi ◽  
Farhad Akbari Afkhami
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Tridentate Ligand ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
Trigonal Bipyramidal ◽  
Centroid Distance ◽  
Distorted Trigonal Bipyramidal Coordination ◽  
Distorted Trigonal Bipyramidal

The title compound, [CdBr2(C13H12N4O)], was obtained from the reaction of Cd(NO3)2·4H2O with methyl(pyridin-2-yl)methanone picolinoylhydrazone and sodium bromide. The Cd2+ cation is ligated by one O atom and two N atoms of the tridentate ligand and two bromide anions, forming a Br2CdN2O polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, non-classical C—H...Br hydrogen bonds are observed. In addition, π–π stacking interactions [centroid–centroid distance = 3.7455 (19) Å] contribute to the stabilization of the crystal structure.

catena-Poly[[dichloridodimethyltin(IV)]-μ-5-methylpyrazine-2-carboxylato-κ3 O:O′,N-[dimethyltin(IV)]]-μ-5-methylpyrazine-2-carboxylato-κ3 O,N:O′]

2007 ◽  
Vol 63 (3) ◽  
pp. m847-m849
Author(s):  
Jun-Ying Li ◽  
Tian-Duo Li
Keyword(s):  
Title Compound ◽  
The Other ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Carboxylate Groups ◽  
Coordination Behaviour ◽  
Distorted Trigonal Bipyramidal

The title compound, [Sn2Cl2(CH3)4(C6H5N2O2)2], forms infinite one-dimensional zigzag chains that propagate in a helical fashion along the c axis via an Sn—O=C—O—Sn—O bridge which involves the carboxylate groups of two methylpyrazinecarboxylate ligands. These display both chelating and bridging coordination behaviour. The asymmetric unit contains two Sn atoms; one adopts a distorted trigonal–bipyramidal geometry, while the other is in a distorted pentagonal–bipyramidal configuration.

Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en)3Sb4S7

1997 ◽  
Vol 52 (3) ◽  
pp. 405-409 ◽  
Author(s):  
Wolfgang Bensch ◽  
Michael Schur
Keyword(s):  
Crystal Structure ◽  
Hydrothermal Synthesis ◽  
Title Compound ◽  
Hydrothermal Conditions ◽  
Synthesis And Crystal Structure ◽  
One Dimensional ◽  
Cation Size

Abstract The reaction of manganese with antimony and sulfur in an aqueous ethylenediamine (en) solution under hydrothermal conditions gives Mn(en)3Sb4S7. The structure of the title compound consists of Mn(en)32+ cations and infinite one-dimensional (Sb4S72-)„ anions forming slabs via long secondary interchain Sb···S bonds. A comparison between phases with polymeric (Sb4S72- )„ anions shows in general a trend towards a lower dimensionality of the thioantimonate assembly with increasing cation size. In the title compound the lowest number of interchain Sb···S interactions is observed among other phases with chainlike Sb4S72- anions.

scholarly journals Crystal structure of [tris(pyridin-2-ylmethyl)amine-κ4N]copper(II) bromide

2016 ◽  
Vol 72 (6) ◽  
pp. 801-804 ◽  
Author(s):  
Emma C. Bridgman ◽  
Megan M. Doherty ◽  
Kaleigh A. Ellis ◽  
Elizabeth A. Homer ◽  
Taylor N. Lashbrook ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Outer Sphere ◽  
Asymmetric Unit ◽  
Positional Disorder ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Counter Ion ◽  
Amine Ligand ◽  
Distorted Trigonal Bipyramidal

In the asymmetric unit of the title compound, [CuBr(C18H18N4)]Br, there are three crystallographically independent cations. One of the cations exhibits positional disorder of the pyridin-2-ylmethyl groups over two sets of sites with refined occupancies of 0.672 (8) and 0.328 (8). The outer-sphere bromine counter-ion is severely disordered over multiple sites. In each cation, the CuIIion is coordinated by the four N atoms of the tris(pyridin-2-ylmethyl)amine ligand and one bromine and adopts a slightly distorted trigonal–bipyramidal geometry.

Bis(cyclopentenylacetato)tetramethyldistannoxane dimer

2006 ◽  
Vol 62 (5) ◽  
pp. m1167-m1169 ◽  
Author(s):  
Aftab Ahmad ◽  
Azim Khan ◽  
Saqib Ali ◽  
Masood Parvez
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Narrow Range ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
A Value ◽  
Centrosymmetric Dimers ◽  
Distorted Trigonal Bipyramidal

The crystal structure of the title compound, tetra-μ2-(cyclopent-2-enyl)acetato-1:2κ2 O:O′;1:3κ2 O:O′;2:4κ2 O:O′;3:4κ2 O:O′-octamethyl-1κ2 C,2κ2 C,3κ2 C,4κ2 C-di-μ3-oxo-1:2:3κ3 O;2:3:4κ3 O-tetratin(IV), [Sn4(CH3)8(C7H9O2)4O2], is composed of discrete centrosymmetric dimers lying about inversion centres. The cyclopentenylacetate ligand shows different modes of coordination with Sn, as a result of which the central Sn2O2 core is fused with two four-membered (Sn2O2) and two six-membered (Sn2O3C) rings. The endocyclic Sn atoms are six-coordinate in a skew-trapezoidal bipyramidal environment. The exocyclic Sn atoms are five-coordinate and show distorted trigonal–bipyramidal geometry. The Sn—C distances lie in a very narrow range [2.095 (4)–2.113 (4) Å], while the Sn—O distances range between 2.030 (3) and 2.280 (3) Å for strong bonds and a value of 2.654 (3) Å for the relatively weak Sn—O bond.

scholarly journals Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m693-m693 ◽  
Author(s):  
Qing-Lan Zhao ◽  
Guo-Peng Li
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Rotational Axis ◽  
Central Ring ◽  
Π Interactions ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

In the title compound, [ZnBr2(C15H11N3)], the ZnIIion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the ZnIIion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction.

Sign in / Sign up

Export Citation Format

Share Document