scholarly journals Oxonium 2-carboxy-3-(2-furyl)acrylate

2009 ◽  
Vol 65 (6) ◽  
pp. o1310-o1310
Author(s):  
Wen-Xian Liang ◽  
Gang Wang ◽  
Zhi-Rong Qu
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Π Interactions

In the title compound, H3O+·C8H5O5−, neighbouring cations and anions are linked by O—H...O hydrogen bonds, forming a one-dimensional chain framework along [001]. The crystal structure is further stabilized by π–π interactions, with centroid–centroid distances of 3.734 (3) Å.

scholarly journals PhenylN-phenylcarbamate

2009 ◽  
Vol 65 (6) ◽  
pp. o1363-o1363 ◽  
Author(s):  
Durre Shahwar ◽  
M. Nawaz Tahir ◽  
M. Sharif Mughal ◽  
Muhammad Akmal Khan ◽  
Naeem Ahmad
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
One Dimensional ◽  
Π Interactions ◽  
Compound C ◽  
Polymeric Chains

In the title compound, C13H11NO2, the aromatic rings are oriented at a dihedral angle of 42.52 (12)°. The crystal structure is stabilized by intermolecular N—H...O hydrogen bonds, which form infinite one-dimensional polymeric chains extending along theaaxis. C—H...π interactions between the aromatic rings are also present.

scholarly journals 4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium nitrate

2009 ◽  
Vol 65 (6) ◽  
pp. o1361-o1361
Author(s):  
Li-Jing Cui
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Dihedral Angles ◽  
Dimensional Chain ◽  
Aromatic Rings ◽  
One Dimensional ◽  
Compound C

In the cation of the title compound, C22H19N2+·NO3−, the N atom in the 3-position of the imidazole is protonated. The three pendant aromatic rings are twisted from the plane of the imadazolium ring by dihedral angles of 38.1 (1), 43.74 (9) and 20.4 (1)°. In the crystal structure, N—H...O and N—H...(O,O) hydrogen bonds link the molecules to form an infinite one-dimensional chain parallel to thecaxis.

catena-Poly[[[aquasilver(I)]-μ-2,3-dimethylpyrazine-κ2 N:N′] 4-amino-2,5-dichlorobenzenesulfonate]

2007 ◽  
Vol 63 (11) ◽  
pp. m2734-m2735
Author(s):  
Hai-Yan Liu ◽  
Ji-Cheng Ma ◽  
Jin Yang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Chain Structure ◽  
Planar Geometry ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Dimensional Network ◽  
Charge Balancing

In the title compound, {[Ag(C6H8N2)(H2O)](C6H4Cl2NO3S)} n , the AgI ion is three-coordinated by two N atoms from two symmetry-related 2,3-dimethylpyrazine (dmp) ligands, and one water O atom in a distorted trigonal–planar geometry. The dmp ligands bridge AgI ions to form a one-dimensional chain structure with charge-balancing 4-amino-2,5-dichlorobenzenesulfonate anions. In the crystal structure, intermolecular O—H...O and N—H...O hydrogen bonds form a two-dimensional network.

(E)-3-(2-Nitriminoimidazolidin-1-yl)-1-phenylpropan-1-one

2007 ◽  
Vol 63 (11) ◽  
pp. o4242-o4242
Author(s):  
Haibo Yu ◽  
Bingnan Zhang ◽  
Jianxin Fang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Imidazole Ring ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Compound C ◽  
Hydrogen Bonding Interactions

In the crystal structure of the title compound, C12H14N4O3, the dihedral angle between the phenyl and imidazole rings is 76.55 (7)°. The nitrite O atoms of the (E)-2-nitriminoimidazolidin-1-yl group act as the acceptors of three N—H...O hydrogen bonds from the N atom of the imidazole ring, resulting in a one-dimensional chain. C—H...O hydrogen-bonding interactions are also observed in this complex, extending the structure into a two-dimensional supramolecular sheet.

2-[(E)-2-(4-Methoxyphenyl)ethenyl]-1-methylquinolinium 4-bromobenzenesulfonate

2006 ◽  
Vol 62 (7) ◽  
pp. o2725-o2727 ◽  
Author(s):  
Hoong-Kun Fun ◽  
Pinanong Rodwatcharapiban ◽  
Boonwasana Jindawong ◽  
Suchada Chantrapromma
Keyword(s):  
Crystal Structure ◽  
Benzene Ring ◽  
Title Compound ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Π Interactions ◽  
Compound C ◽  
Dimensional Network

In the title compound C19H18NO+·C6H4BrSO3 −, the cation is almost planar. The benzene ring of the anion makes dihedral angles of 84.23 (12) and 84.59 (15)°, respectively, with the quinolinium group and the benzene ring of the cation. The cations and anions are arranged in an alternating one-dimensional chain along the b axis, and these chains are interconnected through C—H...O and C—H...Br interactions to form a three-dimensional network. C—H...π interactions are also observed in the crystal structure.

(S)-O-[4-(2,2,4-Trimethylchroman-4-yl)phenyl] N,N-dimethylthiocarbamate

2007 ◽  
Vol 63 (11) ◽  
pp. o4444-o4444 ◽  
Author(s):  
Tia Jacobs ◽  
Martin W. Bredenkamp
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
One Dimensional ◽  
Π Interactions ◽  
Compound C

Crystallization of the (S)-enantiomer of the title compound, C21H26NO2S, from methanol gave an unsolvated crystal structure in which one-dimensional strands of molecules are formed through a series of C—H...O and C—H...S hydrogen bonds, and C—H...π interactions.

scholarly journals Crystal structure of cafenstrole

2015 ◽  
Vol 71 (8) ◽  
pp. o614-o614 ◽  
Author(s):  
Gihaeng Kang ◽  
Jineun Kim ◽  
Hyunjin Park ◽  
Tae Ho Kim
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
One Dimensional ◽  
Π Interactions

The title compound (systematic name:N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide), C16H22N4O3S, is a triazole herbicide. The dihedral angle between the planes of the triazole and benzene ring planes is 88.14 (10)°. In the crystal, C—H...O hydrogen bonds and weak C—H...π interactions link adjacent molecules, forming one-dimensional chains along theaaxis.

scholarly journals Bis(acetato-κ2O,O′)bis(3,5-dimethyl-1H-pyrazole-κN2)copper(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m691-m692 ◽  
Author(s):  
Yuliya M. Davydenko ◽  
Igor O. Fritsky ◽  
Vadim O. Pavlenko ◽  
Franc Meyer ◽  
Sebastian Dechert
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Title Compound ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Pyrazole Ligands

In the title compound, [Cu(C2H3O2)2(C5H8N2)2], the CuIIatom has a distorted tetragonal–bipyramidal geometry, with the equatorial plane formed by two N atoms belonging to two 3,5-dimethyl-1H-pyrazole ligands and two O atoms from two acetate anions. The second O atoms of the acetate groups provide elongated Cu—O axial contacts, so that the acetates appear to be coordinated in a pseudo-chelate fashion. The pyrazole ligands are situated incispositions with respect to each other. In the crystal structure, molecules are linked through intermolecular N—H...O hydrogen bonds, forming a one-dimensional chain.

scholarly journals Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]cobalt(II)

2015 ◽  
Vol 71 (5) ◽  
pp. 452-454 ◽  
Author(s):  
Abdelhakim Laachir ◽  
Fouad Bentiss ◽  
Salaheddine Guesmi ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Maximum Deviation ◽  
Coordination Geometry ◽  
Acta Cryst ◽  
Π Interactions ◽  
The Mean

In the mononuclear title complex, [Co(N3)2(C12H8N4S)2], the cobalt(II) atom is located on an inversion centre and displays an axially weakly compressed octahedral coordination geometry. The equatorial positions are occupied by the N atoms of two 2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole ligands, whereas the axial positions are occupied by N atoms of the azide anions. The thiadiazole and pyridine rings linked to the metal are almost coplanar, with a maximum deviation from the mean plane of 0.0273 (16) Å. The cohesion of the crystal is ensured by weak C—H...N hydrogen bonds and by π–π interactions between pyridine rings [intercentroid distance = 3.6356 (11) Å], forming a layered arrangement parallel to (001). The structure of the title compound is isotypic with that of the analogous nickel(II) complex [Laachiret al.(2013).Acta Cryst.E69, m351–m352].

scholarly journals Crystal structure of 2-benzylamino-4-p-tolyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile

2015 ◽  
Vol 71 (2) ◽  
pp. 192-194
Author(s):  
R. A. Nagalakshmi ◽  
J. Suresh ◽  
S. Maharani ◽  
R. Ranjith Kumar ◽  
P. L. Nilantha Lakshman
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Pyridine Ring ◽  
Three Dimensional ◽  
Π Interactions ◽  
Compound C ◽  
Centroid Distance ◽  
Cyclopentane Ring ◽  
Ring Motif

The title compound, C23H21N3, comprises a 2-amino-3-cyanopyridine ring fused with a cyclopentane ring. The later adopts an envelope conformation with the central methylene C atom as the flap. The benzyl and andp-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, molecules are linked by pairs of N—H...Nnitrilehydrogen bonds, forming inversion dimers with anR22(12) ring motif. The dimers are linked by C—H...π and π–π interactions [centroid–centroid distance = 3.7211 (12) Å], forming a three-dimensional framework.

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