Bis[hexaamminecobalt(III)] pentachloride nitrate
2012 ◽
Vol 68
(6)
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pp. i45-i46
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The title compound, [Co(NH3)6]2Cl5(NO3), was obtained under hydrothermal conditions. The asymmetric unit contains three Co3+ ions, one lying on an inversion center and the other two located at 2/m positions. All Co3+ ions are six-coordinated by NH3 molecules, forming [Co(NH3)6]3+ octahedra, with Co—N distances in the range 1.945 (4)–1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl− anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N—H...O and N—H...Cl hydrogen bonds link the cations and anions into a three-dimensional network.
2012 ◽
Vol 68
(6)
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pp. o1942-o1942
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2013 ◽
Vol 69
(12)
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pp. i83-i83
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2014 ◽
Vol 70
(6)
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pp. m227-m228
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2014 ◽
Vol 70
(3)
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pp. o279-o280
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2012 ◽
Vol 68
(8)
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pp. o2438-o2439
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2014 ◽
Vol 70
(4)
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pp. o445-o445
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2015 ◽
Vol 71
(4)
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pp. 289-293
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2013 ◽
Vol 69
(11)
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pp. o1626-o1627
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2014 ◽
Vol 70
(7)
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pp. m269-m269
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