Bis(μ-diisopropylphosphanido-κ2
P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
2012 ◽
Vol 68
(6)
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pp. m808-m808
In the centrosymmetric molecular structure of the title compound [Pt2(C6H14P)2H2(C9H21P)2], each PtII atom is bound on one side to a phosphane ligand (PiPr3) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr2), which engage a bridging position between the two PtII atoms, forming a distorted square-planar structure motif. The Pt...Pt distance is 3.6755 (2) Å. A comparable molecular structure was observed for bis(μ-di-tert-butylphosphanido)bis[hydrido(triethylphosphane)platinum(II)] [Itazaki et al. (2004). Organometallics, 23, 1610–1621].
2006 ◽
Vol 62
(7)
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pp. m1569-m1571
2006 ◽
Vol 62
(7)
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pp. m1512-m1513
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2007 ◽
Vol 63
(11)
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pp. m2812-m2812
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2013 ◽
Vol 69
(2)
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pp. m96-m96
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1981 ◽
Vol 36
(12)
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pp. 1526-1531
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2015 ◽
Vol 71
(4)
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pp. m83-m84
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1974 ◽
Vol 52
(19)
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pp. 3331-3336
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2007 ◽
Vol 63
(3)
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pp. m728-m730