Bis(1,2-dimethoxyethane)-1κ2O,O′;3κ2O,O′-tetrakis(μ-1,1,1,3,3,3-hexafluoro-2-methylpropan-2-olato)-1:2κ4O:O;2:3κ4O:O-1,3-dilithium-2-magnesium
2012 ◽
Vol 68
(8)
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pp. m1106-m1106
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The title compound, [Li2Mg(C4H3F6O)4(C4H10O2)2], forms as a white crystalline powder by-product of the reaction of lithium 1,1,1,3,3,3-hexafluoro-2-methyl-2-propoxide with Mo(N-2,6-Me2—C6H3)(CHCMe2Ph)(O3SCF3)2·2DME (DME is 1,2-dimethoxyethane) contaminated with MgCl2. The crystal structure of this compound contains half a molecule in the asymmetric unit, with a twofold rotation axis through the central Mg2+cation. The four 1,1,1,3,3,3-hexafluoro-2-methylpropan-2-olate ligands serve as bridging ligands connecting the Li+and Mg2+cations. The Li+cation is additionally stabilized by a DME ligand. This results in a distorted tetrahedral ligand field around both the Mg2+and Li+cations.
2007 ◽
Vol 63
(3)
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pp. m892-m894
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2020 ◽
Vol 76
(9)
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pp. 1525-1527
2015 ◽
Vol 71
(3)
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pp. 258-260
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2014 ◽
Vol 70
(12)
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pp. m401-m402
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2013 ◽
Vol 69
(11)
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pp. m620-m620
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2006 ◽
Vol 62
(5)
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pp. o1851-o1853
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2009 ◽
Vol 65
(6)
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pp. o1294-o1295
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2015 ◽
Vol 71
(12)
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pp. 1436-1438
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2017 ◽
Vol 73
(4)
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pp. 539-542
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