scholarly journals N-(4-Methylphenylsulfonyl)-3-nitrobenzamide

2014 ◽  
Vol 70 (2) ◽  
pp. o191-o191
Author(s):  
S. Sreenivasa ◽  
M. S. Nanjundaswamy ◽  
A. G. Sudha ◽  
K. J. Pampa ◽  
N. K. Lokanath ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Amide Group ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C14H12N2O5S, the dihedral angle between the aromatic rings is 86.29 (1)° and the conformation between the C=O bond of the amide group and themeta-NO2group issyn. The C—S—N—C torsion angle is −65.87 (19)° and the molecule has an L-shaped conformation. In the crystal, the molecules are connected into inversion dimers through pairs of N—H...O hydrogen bonds and C—H...O interactions formingR22(8) andR22(14) loops, respectively. The dimers are connected by further C—H...O interactions, thereby forming (100) sheets.

scholarly journals N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluorobenzenesulfonamide

2012 ◽  
Vol 68 (8) ◽  
pp. o2433-o2433 ◽  
Author(s):  
Shumaila Younas Mughal ◽  
Islam Ullah Khan ◽  
William T. A. Harrison ◽  
Muneeb Hayat Khan ◽  
Muhammad Nadeem Arshad
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C14H12FNO4S, the dihedral angle between the aromatic rings is 50.26 (9)° and the C—S—N—C bond adopts agaucheconformation [torsion angle = −68.12 (15)°]. The dihydrodioxine ring is disordered over two orientations, which both approximate to half-chairs, in a 0.880 (7):0.120 (7) ratio. In the crystal, N—H...O hydrogen bonds link the molecules intoC(4) chains propagating in [100]. Weak C—H...O and C—H...F interactions consolidate the packing.

scholarly journals 2,5-Dichloro-N-(3-methylphenyl)benzenesulfonamide

2012 ◽  
Vol 68 (8) ◽  
pp. o2476-o2476 ◽  
Author(s):  
Shumaila Younas Mughal ◽  
Islam Ullah Khan ◽  
William T. A. Harrison ◽  
Muneeb Hayat Khan ◽  
Muhammad Nadeem Arshad
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C13H11Cl2NO2S, the dihedral angle between the aromatic rings is 76.62 (10)° and the C—S—N—C linkage between the rings adopts agaucheconformation [torsion angle = −51.4 (2)°]. A weak intramolecular C—H...O interaction closes anS(6) ring. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generateR22(8) loops.

scholarly journals 4-Chloro-2-nitro-1-(2-phenylethyl)benzene

IUCrData ◽  
2017 ◽  
Vol 2 (4) ◽  
Author(s):  
N. K. Manjunath ◽  
A. A. Nabil Najib ◽  
P. Nagendra ◽  
B. P Siddaraju ◽  
M. T. Swamy ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Nitro Group ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Compound C ◽  
Cl Atom

In the title compound, C14H12ClNO2, the dihedral angle between the aromatic rings is 6.09 (17)° and the Car—C—C—Cartorsion angle is −179.4 (3)°. The nitro group is close to coplanar with its attached ring [dihedral angle = 7.9 (2)°] and the Cl atom is disordered over two adjacent sites in a 0.54 (4):0.46 (4) ratio. In the crystal, C—H...O hydrogen bonds link the molecules intoC(6) [001] chains.

scholarly journals Crystal structure of (E)-N-{2-[2-(3-chlorobenzylidene)hydrazinyl]-2-oxoethyl}-4-methylbenzenesulfonamide monohydrate

2015 ◽  
Vol 71 (6) ◽  
pp. 602-605 ◽  
Author(s):  
H. Purandara ◽  
Sabine Foro ◽  
B. Thimme Gowda
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Hydrogen Atoms ◽  
Torsion Angles ◽  
Compound C ◽  
Corrugated Sheets

The molecule of the title compound, C16H16ClN3O3S·H2O, is L-shaped being bent at the S atom; the S—N—C—C torsion angle is 132.0 (3)°. The central part of the molecule, C—C—N—N=C, is almost linear, with the C—C—N—N and C—N—N=C torsion angles being −174.1 (2) and 176.0 (2)°, respectively. The dihedral angle between thep-toluenesulfonyl ring and the S—N—C—C(=O) segment is 67.5 (4)°, while that between the two aromatic rings is 52.17 (11)°. In the crystal, the water H atom is involved in O—H...O hydrogen bonds with a sulfonamide O atom and the carbonyl O atom. The water O atom is itself hydrogen bonded to both NH hydrogen atoms. These four hydrogen bonds lead to the formation of corrugated sheets lying parallel to (100). There are also weak C—H...O contacts present within the sheets.

scholarly journals (E)-3-(2,3-Dichlorophenyl)-1-phenylprop-2-en-1-one

IUCrData ◽  
2017 ◽  
Vol 2 (2) ◽  
Author(s):  
S. Naveen ◽  
A. Dileep Kumar ◽  
D. M. Lokeshwari ◽  
K. Ajay Kumar ◽  
N. K. Lokanath ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C15H10Cl2O, the dihedral angle between the aromatic rings is 5.59 (15)° and the C—C=C—C torsion angle is 177.5 (3)°. In the crystal, molecules are linkedviapairs of C—H...O hydrogen bonds, forming inversion dimers withR22(10) ring motifs.

scholarly journals Crystal structure of 4-fluoro-N-[2-(4-fluorobenzoyl)hydrazine-1-carbonothioyl]benzamide

2014 ◽  
Vol 70 (9) ◽  
pp. o915-o916 ◽  
Author(s):  
Syadza Firdausiah ◽  
Ameera Aqeela Salleh Huddin ◽  
Siti Aishah Hasbullah ◽  
Bohari M. Yamin ◽  
Siti Fairus M. Yusoff
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Amide Group ◽  
Compound C

In the title compound, C15H11F2N3O2S, the dihedral angle between the fluorobenzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluorobenzene ring is 50.52 (11)°; the equivalent angle between the carbonylthioamide group and its attached ring is 12.98 (10)°. The major twists in the molecule occur about the C—N—N—C bonds [torsion angle = −138.7 (2)°] and the Car—Car—C—N (ar = aromatic) bonds [−132.0 (2)°]. An intramolecular N—H...O hydrogen bond occurs, which generates anS(6) ring. In the crystal, the molecules are linked by N—H...O and N—H...S hydrogen bonds, generating (001) sheets. Weak C—H...O and C—H...F interactions are also observed.

scholarly journals 2-(2,4-Dinitrophenyl)-1-(pyridin-4-yl)ethanol monohydrate

IUCrData ◽  
2020 ◽  
Vol 6 (2) ◽  
Author(s):  
Houshi Huang ◽  
Zhichao Wu
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C13H11N3O5·H2O, the dihedral angle between the aromatic rings is 9.60 (7)° and the chain linking the rings has an anti conformation with a torsion angle of −178.28 (12)°. In the crystal, the components are linked by O—H...O and O—H...N hydrogen bonds, generating (010) sheets.

scholarly journals Crystal structure of (E)-N′-(3,4-difluorobenzylidene)-4-methylbenzenesulfonohydrazide

2015 ◽  
Vol 71 (10) ◽  
pp. o761-o761
Author(s):  
Yeming Wang ◽  
Hong Yan
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Three Dimensional ◽  
Translational Symmetry ◽  
Aromatic Rings ◽  
Compound C ◽  
Dimensional Network

In the title compound, C14H12F2N2O2S, the dihedral angle between the aromatic rings is 70.23 (8)° and the S—N—N=C torsion angle is 172.11 (11)°. In the crystal, N—H...O hydrogen bonds link the molecules into [100]C(4) chains, with adjacent molecules in the chain related by translational symmetry. The chains are linked by weak C—H...F and C—H...O interactions, thereby forming a three-dimensional network.

scholarly journals N′-(3-Hydroxybenzylidene)-4-methylbenzohydrazide

2012 ◽  
Vol 68 (6) ◽  
pp. o1816-o1816
Author(s):  
Ji-Lai Liu ◽  
Ming-Hui Sun ◽  
Jing-Jun Ma
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Title Compound ◽  
Crystal Packing ◽  
Aromatic Rings ◽  
Π Interactions ◽  
Compound C ◽  
Centroid Distance ◽  
Benzene Rings

The title compound, C15H14N2O2, was obtained from the reaction of 3-hydroxybenzaldhyde and 4-methylbenzohydrazide in methanol. In the molecule, the benzene rings form a dihedral angle of 2.9 (3)°. In the crystal, N—H...O and O—H...O hydrogen bonds link the molecules into layers parallel to (101). The crystal packing also exhibits π–π interactions between the aromatic rings [centroid–centroid distance = 3.686 (4) Å].

scholarly journals Crystal structure of diethyl [(4-chloroanilino)(4-hydroxyphenyl)methyl]phosphonateN,N-dimethylformamide monosolvate

2014 ◽  
Vol 70 (9) ◽  
pp. o919-o920
Author(s):  
Qing-Ming Wang ◽  
Ming-Juan Zhu ◽  
Jin-Ming Yang ◽  
Shan-Shan Wang ◽  
Yan-Fang Shang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Title Compound ◽  
Double Layers ◽  
Aromatic Rings ◽  
Compound C

In the title compound, C17H21ClNO4P·C3H7NO, the dihedral angle formed by the aromatic rings is 83.98 (7)°. In the crystal, O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into double layers parallel to (011).

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