A new polymorph of aquabis(1,10-phenanthroline-κ2N,N′)copper(II) dinitrate
2014 ◽
Vol 70
(5)
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pp. m185-m186
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Keyword(s):
The title molecule, [Cu(C12H8N2)2(H2O)](NO3)2, is a new polymorph of a compound which up to now has been reported to crystallize space groups inC2/candCc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined inP-1. The CuIIatom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water molecule in an approximate trigonal–bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water–nitrate O—H...O hydrogen bonds. The components are further assembled into a three-dimensional network by C—H...O hydrogen bonds.
2014 ◽
Vol 70
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pp. m190-m191
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2012 ◽
Vol 68
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pp. m1029-m1029
2014 ◽
Vol 70
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pp. m75-m75
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Keyword(s):
2006 ◽
Vol 62
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pp. m1719-m1721
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2015 ◽
Vol 71
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pp. 520-522
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2007 ◽
Vol 63
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pp. o1121-o1122
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2015 ◽
Vol 71
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pp. m85-m86
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2012 ◽
Vol 68
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pp. m847-m848
2014 ◽
Vol 70
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pp. o398-o399
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Keyword(s):
2006 ◽
Vol 62
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pp. m1535-m1537
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