Crystal structure of tris(phenylselenolato-κSe)tris(tetrahydrofuran-κO)thulium(III)
2014 ◽
Vol 70
(11)
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pp. m389-m389
Keyword(s):
In the title compound, [Tm(C6H5Se)3(C4H8O)3], the TmIIIatom lies on a threefold rotation axis and is coordinated by three phenylselenolate ligands and three tetrahydrofuran ligands leading to a distortedfac-octahedral coordination environment. The Tm—Se and Tm—O bond lengths are 2.7692 (17) and 2.345 (10) Å, respectively, and the bond angles are 91.32 (6)° for Se—Tm—Se, 92.6 (2) and 94.4 (2)° for Se—Tm—O, and 81.2 (3)° for O—Tm—O. In the crystal, the discrete complexes are linked by van der Waals interactions only. The crystal was refined as a non-merohedral twin (ratio = 0.65:0.35).
2007 ◽
Vol 63
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pp. o1145-o1147
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2017 ◽
Vol 73
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pp. 1121-1124
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2007 ◽
Vol 63
(11)
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pp. o4357-o4357
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2014 ◽
Vol 70
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pp. 246-248
2007 ◽
Vol 63
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pp. o1459-o1461
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Keyword(s):
2020 ◽
Vol 76
(9)
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pp. 1525-1527
2012 ◽
Vol 68
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pp. o1894-o1894
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2006 ◽
Vol 62
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pp. o2714-o2716
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Keyword(s):
2012 ◽
Vol 68
(12)
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pp. o485-o487
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2022 ◽
Vol 78
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