scholarly journals Simultaneous two-color X-ray absorption spectroscopy using Laue crystals at an inverse-compton scattering X-ray facility

2021 ◽  
Vol 28 (6) ◽  
Author(s):  
Juanjuan Huang ◽  
Benedikt Günther ◽  
Klaus Achterhold ◽  
Martin Dierolf ◽  
Franz Pfeiffer
Keyword(s):  
Compton Scattering ◽  
Absorption Spectroscopy ◽  
Bimetallic Catalyst ◽  
Structural Information ◽  
Synergistic Effects ◽  
Edge Structure ◽  
X Ray ◽  
Inverse Compton Scattering ◽  
Inverse Compton ◽  
X Ray Absorption

X-ray absorption spectroscopy (XAS) is an element-selective technique that provides electronic and structural information of materials and reveals the essential mechanisms of the reactions involved. However, the technique is typically conducted at synchrotrons and usually only probes one element at a time. In this paper, a simultaneous two-color XAS setup at a laboratory-scale synchrotron facility is proposed based on inverse Compton scattering (ICS) at the Munich Compact Light Source (MuCLS), which is based on inverse Compton scattering (ICS). The setup utilizes two silicon crystals in a Laue geometry. A proof-of-principle experiment is presented where both silver (Ag) and palladium (Pd) K-edge X-ray absorption near-edge structure spectra were simultaneously measured. The simplicity of the setup facilitates its migration to other ICS facilities or maybe to other X-ray sources (e.g. a bending-magnet beamline). Such a setup has the potential to study reaction mechanisms and synergistic effects of chemical systems containing multiple elements of interest, such as a bimetallic catalyst system.

scholarly journals Laboratory-Scale in situ X-Ray Absorption Spectroscopy of a Palladium Catalyst on a Compact Inverse-Compton Scattering X-Ray Beamline

2021 ◽  
Author(s):  
Juanjuan Huang ◽  
Fuli Deng ◽  
Benedikt Günther ◽  
Klaus Achterhold ◽  
Yue Liu ◽  
...  
Keyword(s):  
Compton Scattering ◽  
Absorption Spectroscopy ◽  
Palladium Catalyst ◽  
Catalyst Characterization ◽  
X Ray ◽  
Inverse Compton Scattering ◽  
In Situ Conditions ◽  
Inverse Compton ◽  
X Ray Absorption

X-ray absorption spectroscopy (XAS) is one of the most important techniques used for catalyst characterization, and is often conducted under in-situ conditions. Such experiments are typically carried out at synchrotrons,...

Visualization of microvessels by angiography using inverse-Compton scattering X-rays in animal models

2014 ◽  
Vol 21 (6) ◽  
pp. 1327-1332 ◽  
Author(s):  
Toshiharu Fujii ◽  
Naoto Fukuyama ◽  
Chiharu Tanaka ◽  
Yoshimori Ikeya ◽  
Yoshiro Shinozaki ◽  
...  
Keyword(s):  
Compton Scattering ◽  
Photon Number ◽  
High Gain ◽  
Image Sensor ◽  
Clinical Settings ◽  
X Rays ◽  
X Ray ◽  
Inverse Compton Scattering ◽  
Small Vessels ◽  
Inverse Compton

The fundamental performance of microangiography has been evaluated using the S-band linac-based inverse-Compton scattering X-ray (iCSX) method to determine how many photons would be required to apply iCSX to human microangiography. ICSX is characterized by its quasi-monochromatic nature and small focus size which are fundamental requirements for microangiography. However, the current iCSX source does not have sufficient flux for microangiography in clinical settings. It was determined whether S-band compact linac-based iCSX can visualize small vessels of excised animal organs, and the amount of X-ray photons required for real time microangiography in clinical settings was estimated. The iCSX coupled with a high-gain avalanche rushing amorphous photoconductor camera could visualize a resolution chart with only a single iCSX pulse of ∼3 ps duration; the resolution was estimated to be ∼500 µm. The iCSX coupled with an X-ray cooled charge-coupled device image sensor camera visualized seventh-order vascular branches (80 µm in diameter) of a rabbit ear by accumulating the images for 5 and 30 min, corresponding to irradiation of 3000 and 18000 iCSX pulses, respectively. The S-band linac-based iCSX visualized microvessels by accumulating the images. An iCSX source with a photon number of 3.6 × 103–5.4 × 104times greater than that used in this study may enable visualizing microvessels of human fingertips even in clinical settings.

scholarly journals Nested Kirkpatrick–Baez (Montel) optics for hard X-rays

2015 ◽  
Vol 48 (2) ◽  
pp. 558-564 ◽  
Author(s):  
Giacomo Resta ◽  
Boris Khaykovich ◽  
David Moncton
Keyword(s):  
Ray Tracing ◽  
Compton Scattering ◽  
Analytical Procedure ◽  
X Rays ◽  
Multilayer Mirrors ◽  
Comprehensive Description ◽  
X Ray ◽  
Inverse Compton Scattering ◽  
Inverse Compton ◽  
Proper Orientation

A comprehensive description and ray-tracing simulations are presented for symmetric nested Kirkpatrick–Baez (KB) mirrors, commonly used at synchrotrons and in commercial X-ray sources. This paper introduces an analytical procedure for determining the proper orientation between the two surfaces composing the nested KB optics. This procedure has been used to design and simulate collimating optics for a hard-X-ray inverse Compton scattering source. The resulting optical device is composed of two 12 cm-long parabolic surfaces coated with a laterally graded multilayer and is capable of collimating a 12 keV beam with a divergence of 5 mrad (FWHM) by a factor of ∼250. A description of the ray-tracing software that was developed to simulate the graded multilayer mirrors is included.

X-ray absorption spectroscopy and density functional analysis of the Fe3+ distribution profile on Al sites in a chrysoberyl crystal, BeAl2O4:Fe3+

2016 ◽  
Vol 49 (2) ◽  
pp. 385-388 ◽  
Author(s):  
Kanokwan Kanchiang ◽  
Atipong Bootchanont ◽  
Janyaporn Witthayarat ◽  
Sittichain Pramchu ◽  
Panjawan Thanasuthipitak ◽  
...  
Keyword(s):  
Optical Properties ◽  
Absorption Spectroscopy ◽  
Density Functional ◽  
Density Functional Theory Calculations ◽  
Distribution Profile ◽  
Laser Applications ◽  
Edge Structure ◽  
X Ray ◽  
Site Distribution ◽  
X Ray Absorption

Chrysoberyl is one of the most interesting minerals for laser applications, widely used for medical purposes, as it exhibits higher laser performance than other materials. Although its utilization has been vastly expanded, the location of transition metal impurities, especially the iron that is responsible for chrysoberyl's special optical properties, is not completely understood. The full understanding and control of these optical properties necessitates knowledge of the precise location of the transition metals inside the structure. Therefore, synchrotron X-ray absorption spectroscopy (XAS), a local structural probe sensitive to the different local geometries, was employed in this work to determine the site occupation of the Fe3+ cation in the chrysoberyl structure. An Fe K-edge X-ray absorption near-edge structure (XANES) simulation was performed in combination with density functional theory calculations of Fe3+ cations located at different locations in the chrysoberyl structure. The simulated spectra were then qualitatively compared with the measured XANES features. The comparison indicates that Fe3+ is substituted on the two different Al2+ octahedral sites with the proportion 60% on the inversion site and 40% on the reflection site. The accurate site distribution of Fe3+ obtained from this work provides useful information on the doping process for improving the efficiency of chrysoberyl as a solid-state laser material.

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