Crystal structure and computational study of an oxo-bridged bis-titanium(III) complex
2021 ◽
Vol 77
(7)
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Keyword(s):
The solid-state structure of the new compound μ-oxido-bis[dichloridotris(tetrahydrofuran-κO)titanium(III)], [Ti2Cl4O(C4H8O)6], at 150 K has been determined. The crystal has monoclinic (C2/c) symmetry and the complex features C 2 symmetry about the bridging O atom. Positional disorder is evident in one of the three tetrahydrofuran environments. A post-Hartree–Fock computational analysis indicates that the complex has nearly degenerate triplet and singlet spin states, with the former favoured slightly by ca 2 kJ mol−1.
2015 ◽
Vol 71
(10)
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pp. o697-o698
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Keyword(s):
1995 ◽
Vol 210
(11)
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Keyword(s):
Keyword(s):
2006 ◽
Vol 59
(11)
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pp. 1253-1260
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Keyword(s):
2006 ◽
Vol 62
(4)
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pp. o1300-o1301
Keyword(s):
1995 ◽
Vol 32
(2)
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pp. 451-456
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Keyword(s):
1988 ◽
pp. 1045
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2016 ◽
Vol 72
(12)
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pp. 1754-1756
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2015 ◽
Vol 71
(11)
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pp. o852-o853
2000 ◽
Vol 54
(4)
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pp. 249-261
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