Crystal structure of hexakis(dimethylformamide-κO)manganese(II) decakis(dimethylformamide)-1κ5O,2κ5O-[μ-octadecatungstodiphosphato(V)-κO:κO′]dimanganate(II) dimethylformamide disolvate
2016 ◽
Vol 72
(6)
◽
pp. 841-844
◽
Keyword(s):
The crystal structure of the title compound, [Mn(C3H7NO)6][{Mn(C3H7NO)5}2(μ-P2W18O62)]·2C3H7NO, reveals that the Wells–Dawson-type polyanion [P2W18O62]6−, through terminal O atoms from the belts, bridges two MnIIoctahedral complexes. In the complex anion [{Mn(dmf)5}2(μ-P2W18O62)]2−, located around a twofold rotation axis, the MnIIions are coordinated by five O atoms from dimethylformamide (dmf) ligands and to a terminal O atom from the [P2W18O62]6−polyanion. Another MnIIion, located on an inversion centre, is coordinated by six O atoms from the dmf ligands and forms the [Mn(dmf)6]2+cation. The crystal components are connected through numerous weak C—H...O hydrogen bonds to construct a three-dimensional network.
2016 ◽
Vol 72
(8)
◽
pp. 1219-1222
Keyword(s):
2014 ◽
Vol 70
(10)
◽
pp. o1130-o1130
◽
Keyword(s):
2015 ◽
Vol 71
(10)
◽
pp. o719-o720
◽
Keyword(s):
Keyword(s):
2015 ◽
Vol 71
(12)
◽
pp. m275-m276
◽
Keyword(s):
2014 ◽
Vol 70
(9)
◽
pp. o1029-o1030
Keyword(s):
2014 ◽
Vol 70
(10)
◽
pp. o1106-o1106
Keyword(s):
2007 ◽
Vol 63
(3)
◽
pp. o1121-o1122
Keyword(s):
2015 ◽
Vol 71
(4)
◽
pp. m85-m86
◽
2006 ◽
Vol 62
(4)
◽
pp. o1488-o1489
Keyword(s):