Crystal structure of thecisandtranspolymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
2017 ◽
Vol 73
(2)
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pp. 310-313
Keyword(s):
The title dinuclear complex, [Re2(C13H8NOS)2(CO)6], crystallizes in two polymorphs where the 2-(1,3-benzothiazol-2-yl)phenolate ligands and two carbonyl groups aretrans- (I) orcis-arranged (II) with respect to the [Re2O2(CO)4] core. PolymorphsIandIIexhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structures may be described as being formed by two octahedrally distorted metal-coordinating units fused through μ-oxido bridges, leading to edge-sharing dimers. The crystal packing is governed by C—H...O hydrogen-bonding interactions, forming chains parallel to thecaxis inIand a three-dimensional network inII.
2016 ◽
Vol 72
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pp. 102-105
2016 ◽
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pp. 922-925
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2015 ◽
Vol 71
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pp. m275-m276
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Keyword(s):
2006 ◽
Vol 62
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pp. m796-m798
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2015 ◽
Vol 71
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pp. 73-75
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2007 ◽
Vol 63
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pp. m761-m763
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2020 ◽
Vol 76
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pp. 180-185
2017 ◽
Vol 73
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pp. 28-30
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2012 ◽
Vol 68
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pp. o405-o407
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2014 ◽
Vol 70
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pp. o966-o967