Acetonyltriphenylphosphonium 2,3,5-triphenyltetrazolium tetrachloridocuprate(II)
2018 ◽
Vol 74
(1)
◽
pp. 69-71
◽
Keyword(s):
The title compound, (C21H20OP)(C19H15N4)[CuCl4], was obtained by reacting CuCl2·2H2O with a mixture of one equivalent of acetonyltriphenylphosphonium chloride and one equivalent of 2,3,5-triphenyltetrazolium chloride in acetonitrile. In the structure, the Cu centre in the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The phosphonium cation likewise adopts the expected tetrahedral geometry. The tetrazolium ring forms dihedral angles of 77.68 (10), 26.85 (11) and 66.48 (10)° with the planes of the benzene rings of the substituent groups. In the crystal, weak C—H...Cl hydrogen-bonding interactions involving both cations and the anion give rise to a three-dimensional supramolecular structure.
2013 ◽
Vol 69
(11)
◽
pp. m608-m608
2017 ◽
Vol 73
(4)
◽
pp. 524-527
2014 ◽
Vol 70
(3)
◽
pp. o279-o280
Keyword(s):
2012 ◽
Vol 68
(8)
◽
pp. o2598-o2599
Keyword(s):
2017 ◽
Vol 73
(8)
◽
pp. 1189-1191
◽
Keyword(s):
2013 ◽
Vol 69
(2)
◽
pp. o167-o168
◽
Keyword(s):
2009 ◽
Vol 65
(6)
◽
pp. o1225-o1225
2007 ◽
Vol 63
(11)
◽
pp. m2703-m2704
◽
2013 ◽
Vol 69
(11)
◽
pp. o1716-o1716
Keyword(s):