Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands
2019 ◽
Vol 75
(3)
◽
pp. 378-382
Keyword(s):
Reaction in gel between the sodium salt of 1,4-phenylenediacetic acid (Na2C10O4H8–Na2 p-pda) and lanthanum chloride yields single crystals of the three-dimensional coordination polymer poly[[tetraaquatris(μ-1,4-phenylenediacetato)dilanthanum(III)] octahydrate], {[La2(C10H8O4)3(H2O)4]·8H2O}∞. The LaIII coordination polyhedron can be described as a slightly distorted monocapped square antiprism. One of the two p-pda2− ligands is bound to four LaIII ions and the other to two LaIII ions. Each LaIII atom is coordinated by five ligands, thereby generating a metal–organic framework with potential porosity properties.
2013 ◽
Vol 39
(8)
◽
pp. 588-592
2013 ◽
Vol 39
(2)
◽
pp. 157-160
Keyword(s):
2007 ◽
Vol 23
◽
pp. x1-x2
◽
2008 ◽
Vol 11
(10)
◽
pp. 1143-1146
◽
2005 ◽
Vol 8
(6-7)
◽
pp. 1005-1010
◽
2014 ◽
Vol 45
(1)
◽
pp. 112-116
◽
2018 ◽
Vol 10
(10)
◽
pp. 963-974
2011 ◽
Vol 68
(1)
◽
pp. m4-m6
◽