cis-Bromido(n-butylamine-κN)bis(ethene-1,2-diamine-κ2
N,N′)cobalt(III) dibromide
Keyword(s):
In the title compound, [CoBr(C2H8N2)2(C4H11N)]Br2, the cobalt(III) ion has a distorted octahedral coordination environment and is surrounded by four N atoms in the equatorial plane made up of three N atoms from the two ethylenediamine ligands and the remaining N from the n-butyl substituent, with the other N atom from the ethylenediamine ligand and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter-anions are linked via N—H...Br and C—H...Br hydrogen bonds, forming a three-dimensional network. The crystal studied was refined as a two-component inversion twin.
2012 ◽
Vol 68
(6)
◽
pp. m711-m712
2015 ◽
Vol 71
(8)
◽
pp. 934-936
◽
2009 ◽
Vol 65
(6)
◽
pp. m618-m618
◽
2016 ◽
Vol 72
(12)
◽
pp. 1768-1770
◽
2015 ◽
Vol 71
(11)
◽
pp. 1336-1339
◽
2015 ◽
Vol 71
(6)
◽
pp. m135-m136
2015 ◽
Vol 71
(2)
◽
pp. 195-198
◽
2006 ◽
Vol 62
(7)
◽
pp. m1668-m1670
◽