The vaporization and liquefied coal has important value to answer oil crisis for us, in technological chain support ,The coal chemical industry chain extension dependent on coal chemical industry innovation service system construction. In this paper,the author settled the coal chemical industry and technological innovation service system construction of research and development present situation, puts forward a ultimate extension of the technological chain is mature coal gasification technology, in industry chain the core industry is coal gas industry in the future,While improving the coal chemical industry innovation service system can effectively support technological chain the realization of the goal technique, also can promote the formation of the core industry chain.