This paper investigates the performance analysis of OQPSK in HF band for wireless sensor networks. An analytical model for getting symbol error rate (SER) is given in presence of Bi-Kappa noise in HF band. And the SER of OQPSK is given in AWGN and Rayleigh fading channel. Simulation results HF noise as Bi-Kappa noise should be investigated in HF band for WSN.