Gas Turbine Cycles With Solid Oxide Fuel Cells—Part II: A Detailed Study of a Gas Turbine Cycle With an Integrated Internal Reforming Solid Oxide Fuel Cell

1994 ◽  
Vol 116 (4) ◽  
pp. 312-318 ◽  
Author(s):  
S. P. Harvey ◽  
H. J. Richter

In conventional energy conversion processes, the fuel combustion is usually highly irreversible, and is thus responsible for the low overall efficiency of the power generation process. The energy conversion efficiency can be improved if immediate contact of air and fuel is prevented. One means to prevent this immediate contact is the use of fuel cell technology. Significant research is currently being undertaken to develop fuel cells for large-scale power production. High-temperature solid oxide fuel cells (SOFC) have many features that make them attractive for utility and industrial applications. However, in view of their high operating temperatures and the incomplete nature of the fuel oxidation process, such fuel cells must be combined with conventional power generation technology to develop power plant configurations that are both functional and efficient. Most fuel cell cycles proposed in the literature use a high-temperature fuel cell running at ambient pressure and a steam bottoming cycle to recover the waste heat generated by the fuel cell. With such cycles, the inherent flexibility and shorter start-up time characteristics of the fuel cell are lost. In Part I of this paper (Harvey and Richter, 1994), a pressurized cycle using a solid oxide fuel cell and an integrated gas turbine bottoming cycle was presented. The cycle is simpler than most cycles with steam bottoming cycles and more suited to flexible power generation. In this paper, we will discuss this cycle in more detail, with an in-depth discussion of all cycle component characteristics and losses. In particular, we will make use of the fuel cell’s internal fuel reforming capability. The optimal cycle parameters were obtained based on calculations performed using Aspen Technology’s ASPEN PLUS process simulation software and a fuel cell simulator developed by Argonne National Laboratory (Ahmed et al., 1991). The efficiency of the proposed cycle is 68.1 percent. A preliminary economic assessment of the cycle shows that it should compare favorably with a state-of-the-art combined cycle plant on a cost per MWe basis.

2016 ◽  
Vol 4 (12) ◽  
pp. 4603-4609 ◽  
Author(s):  
Bin Hua ◽  
Meng Li ◽  
Yi-Fei Sun ◽  
Ya-Qian Zhang ◽  
Ning Yan ◽  
...  

In this work, a novel on-cell micro-reformer and the NiSn bimetallic nanoparticles were introduced into a solid oxide fuel cell for efficient conversion of biogas.


1994 ◽  
Vol 116 (4) ◽  
pp. 305-311 ◽  
Author(s):  
S. P. Harvey ◽  
H. J. Richter

In conventional energy conversion processes, the fuel combustion is usually highly irreversible, and is thus responsible for the low overall efficiency of the power generation process. The energy conversion efficiency of the combustion process can be improved if immediate contact of fuel and oxygen is prevented and an oxygen carrier is used. In a previous paper (Harvey et al., 1992), a gas turbine cycle was investigated in which part of the exhaust gases—consisting mainly of CO2, H2O, and N2—are recycled and used as oxygen-carrying components. For the optimized process, a theoretical thermal efficiency of 66.3 percent was achieved, based on the lower heating value (LHV) of the methane fuel. A detailed second-law analysis of the cycle revealed that, although the exergy losses associated with the fuel oxidation were significantly less than those associated with conventional direct fuel combustion methods, these losses were still a major contributor to the overall losses of the system. One means to further improve the exergetic efficiency of a power cycle is to utilize fuel cell technology. Significant research is currently being undertaken to develop fuel cells for large-scale power production. High-efficiency fuel cells currently being investigated use high-temperature electrolytes, such as molten carbonates (~ 650°C) and solid oxides (usually doped zirconia, ~1000°C). Solid oxide fuel cells (SOFC) have many features that make them attractive for utility and industrial applications. In this paper, we will therefore consider SOFC technology. In view of their high operating temperatures and the incomplete nature of the fuel oxidation process, fuel cells must be combined with conventional power generation technology to develop power plant configurations that are both functional and efficient. In this paper, we will show how monolithic SOFC (MSOFC) technology may be integrated into the previously described gas turbine cycle using recycled exhaust gases as oxygen carriers. An optimized cycle configuration will be presented based upon a detailed cycle analysis performed using Aspen Plus™ process simulation software (Aspen Technology, 1991) and a MSOFC fuel cell simulator developed by Argonne National Labs (Ahmed et al., 1991). The optimized cycle achieves a theoretical thermal efficiency of 77.7 percent, based on the LHV of the fuel.


RSC Advances ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 7-14
Author(s):  
Cheng Cheng Wang ◽  
Mortaza Gholizadeh ◽  
Bingxue Hou ◽  
Xincan Fan

Strontium segregation in a La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) electrode reacts with Cr and S in a solid oxide fuel cell (SOFC), which can cause cell performance deterioration.


2017 ◽  
Vol 10 (4) ◽  
pp. 964-971 ◽  
Author(s):  
Yu Chen ◽  
Yan Chen ◽  
Dong Ding ◽  
Yong Ding ◽  
YongMan Choi ◽  
...  

A hybrid catalyst coating dramatically enhances the electrocatalytic activity and durability of a solid oxide fuel cell cathode.


2020 ◽  
Vol 8 (48) ◽  
pp. 25978-25985
Author(s):  
Jun Li ◽  
Jie Hou ◽  
Xiuan Xi ◽  
Ying Lu ◽  
Mingming Li ◽  
...  

Symmetrical solid oxide fuel cell reactor with BaZr0.1Ce0.7Y0.1Yb0.1O3−δ as electrolyte and La0.6Sr0.4Fe0.8Nb0.1Cu0.1O3−δ as electrodes is applied to cogenerate ethylene and electricity.


Sign in / Sign up

Export Citation Format

Share Document