Nonlinear Anelastic Behavior of a Synthetic Rubber at Finite Strains

1978 ◽  
Vol 22 (3) ◽  
pp. 239-258 ◽  
Author(s):  
D. Derman ◽  
Z. Zaphir ◽  
S. R. Bodner

1977 ◽  
Author(s):  
D. Derman ◽  
Z. Zaphir ◽  
S. R. Bodner






1989 ◽  
Vol 62 (5) ◽  
pp. 957-972
Author(s):  
A. Y. Coran ◽  
F. Ignatz-Hoover ◽  
L. H. Davis

Abstract Rubbery vinylpyridine-butadiene copolymers, containing 20–65% by weight of vinylpyridine monomer units, are effective coactivators of vulcanization for TBBS-accelerated sulfur-vulcanized SBR. In addition to emulsion SBR, the new co-activator has been evaluated in copositions of solution SBR, BR, NR, and various blends. The co-activator is active in all of the compositions which contain butadiene-derived synthetic rubber. This includes blends such as SBR/BR, solution-SBR/BR, SBR/NR, BR/NR, SBR/BR/NR, etc. There is little or no activity in which NR is the only polymer. The most efficacious copolymers contain between 30 and 60% 2-vinylpyridine. The incorporation of such a copolymer into an unvulcanized butadiene-derived rubber mix can give a substantial increase in the rate of crosslink formation with only a minimum loss of scorch resistance. Since the polymeric coactivators are very high in molecular weight, it can be at least tentatively concluded that they will not migrate from one component stock to another in a built-up multi-stock rubber article, either before or during vulcanization. Since the curing characteristics of a vinylpyridine-copolymer-containing TBBS-accelerated stock can be similar to those of TBBS-accelerated NR, it might be concluded that the new additives will solve some of the problems in balancing the cures of adjacent NR and SBR stocks in a multicomponent cured rubber article.





PAMM ◽  
2007 ◽  
Vol 7 (1) ◽  
pp. 4060025-4060026
Author(s):  
Christian Fell ◽  
Bernhard Eidel


Sign in / Sign up

Export Citation Format

Share Document