STRAIN RATE–DEPENDENT BEHAVIOR OF UNCURED RUBBER: EXPERIMENTAL INVESTIGATION AND CONSTITUTIVE MODELING

ABSTRACT The strain rate dependence of uncured rubber is investigated through a series of tensile tests (monotonic, multistep relaxation, cyclic creep tests) at different strain rates. In addition, loading/unloading tests in which the strain rate is varied every cycle are carried out to observe their dependence on the deformation history. A strain rate–dependent viscoelastic–viscoplastic constitutive model is proposed with the nonlinear viscosity and process-dependent recovery properties observed in the test results. Those properties are implemented by introducing evolution equations for additional internal variables. The identified material parameters capture the experiments qualitatively well. The proposed model is also evaluated by finite element simulations of the building process of a tire, followed by the in-molding.

FOAMING AND MOISTURE CROSSLINKING OF VINYL TRIETHOXY SILANE GRAFTED ETHYLENE–PROPYLENE–DIENE TERPOLYMER

ABSTRACT Moisture crosslinking of polyolefins has attracted increasing attention because of its high efficiency, low cost, and easy processing. However, the crucial shortcoming of moisture crosslinking is that the side reaction of peroxide scorch (precrosslinking) simultaneously occurs in silane grafting. It has been recognized that making peroxide precrosslinking useful is an effective way to broaden the application of moisture crosslinking. A novel foaming process combined with moisture crosslinking is proposed. The matrix of ethylene–propylene–diene terpolymer grafted with silane vinyl triethoxysilane (EPDM-g-VTES) was prepared by melt grafting, with dicumyl peroxide as initiator. Foaming was then carried out with azodicarbonamide (AC) as the blowing agent by making use of precrosslinking. Subsequently, the EPDM-g-VTES foams were immersed in a water bath to achieve moisture crosslinking with dibutyl tin dilaurate as the catalyst. The results showed that VTES was grafted onto EPDM and the EPDM-g-VTES foams were successfully crosslinked by moisture. The EPDM-g-VTES compounds with AC obtained great cells by compression molding with the help of precrosslinking. The mechanical property of the EPDM-g-VTES foam was improved by moisture crosslinking. The moisture-cured foam with 4 wt% AC had an expansion ratio of about three times, which could bear large deformation and showed a high energy-absorption effect.

SPECIALTY NATURAL RUBBER LATEX FOAM: FOAMABILITY STUDY AND FABRICATION PROCESS

ABSTRACT Specialty natural rubber (SpNR) latex, namely, deproteinized natural rubber (DPNR) latex and epoxidized natural rubber (ENR) latex, has been produced to meet specific product's requirements. However, SpNR is normally used in the form of block rubber to manufacture dry rubber products such as tires and automotive parts. The applications of SpNR latex into latex foam products will be diversified. Findings indicate that foamability of SpNR latex is lower compared to normal latex (LATZ) but shows longer stability time after foamed. Findings also indicate that foam collapse and foam coagulate are two main challenges in the fabrication process of SpNR latex foam. Despite these challenges, SpNR latex foam can be fabricated at different density levels. During the foaming process, additional foaming agent is required to fabricate a SpNR latex foam, which is different from fabricating a normal NR latex foam, especially at low latex foam density. Consequently, a higher level of sodium silicofluoride, used as the gelling agent, is required to set the cell structure of the foam. Findings also indicate that foam density influenced the gelling time and volume shrinkage of the SpNR latex foam. An ideal compounding, foaming, and gelling formulation to fabricate SpNR latex foam via Dunlop batch foaming process has been developed. Morphological study showed that all latex foams are open-cell structure, with lower density foam exhibiting higher porosity and mean pore size. Comparison on hysteresis behavior between DPNR and ENR latex foam indicated that ENR latex foam exhibits higher hysteresis loss ratio compared to DPNR latex foam.

NUMERICAL ANALYSIS OF HEAT TRANSFER AND CHEMICAL REACTION COUPLING IN THE RUBBER SEAL VULCANIZATION PROCESS

ABSTRACT Vulcanization parameters significantly affect the performance of rubber seals and the energy savings of the manufacturing process, which require a relationship between process parameters and vulcanization characteristics. Based on the vulcanization kinetics of rubber seal materials, a transient thermochemical-coupled finite-element model of the vulcanization process was established and solved. Changes in thermal conductivity and specific heat capacity during vulcanization were considered in detail. The effects of operational and structural parameters, such as mold temperature, heating duration, and rubber seal shape, cross-sectional dimensions on vulcanization characteristics were investigated. Finally, feasible suggestions for the vulcanization production of rubber seals are discussed. The study is expected to design parameters and control the vulcanization process of rubber seals accurately.

CHANGES IN THE MECHANICAL, MICRO-, AND NANO-STRUCTURAL PROPERTIES OF REINFORCED VULCANIZED NATURAL RUBBER COMPOUNDS: THEIR DEPENDENCE ON THE SiO2/CB RATIO

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ASSESSMENT OF A NEW ISOTROPIC HYPERELASTIC CONSTITUTIVE MODEL FOR A RANGE OF RUBBERLIKE MATERIALS AND DEFORMATIONS

ABSTRACT The choice of an appropriate strain energy function W is key to accurate modeling and computational finite element analysis of the mechanical behavior of unfilled non-crystalizing rubberlike materials. Despite the existing variety of models, finding a suitable model that can capture many deformation modes of a rubber specimen with a single set of parameter values and satisfy the a priori mathematical and structural requirements remains a formidable task. Previous work proposed a new generalized neo-Hookean W (I1) function, showing a promising fitting capability and enjoying a structural basis. We now use two extended forms of that model that include an I1 term adjunct, W (I1, I2), for application to various boundary value problems commonly encountered in rubber mechanics applications. Specifically, two functional forms of the I2 invariant are considered: a linear function and a logarithmic function. The boundary value problems of interest include the in-plane uniaxial, equi-biaxial, and pure shear deformations and simple shear, inflation, and nonhomogeneous deformations such as torsion. By simultaneous fitting of each model to various deformation modes of rubber specimens, it is demonstrated that a single set of model parameter values favorably captures the mechanical response for all the considered deformations of each specimen. It is further shown that the model with a logarithmic I2 function provides better fits than the linear function. Given the functional simplicity of the considered W (I1, I2) models, the low number of model parameters (three in total), the structurally motivated bases of the models, and their capability to capture the mechanical response for various deformations of rubber specimens, the considered models are recommended as a powerful tool for practical applications and analysis of rubber elasticity.

ISSUES WITH APPROACHES FOR SIMULATING AGING OF NUCLEAR POWER PLANT CABLE MATERIALS

ABSTRACT Over the past 20 y, the International Electrotechnical Commission and the International Atomic Energy Agency have published several Technical Documents describing recommended methods for carrying out accelerated radiation plus temperature aging of cable materials in nuclear power plants. These methods include the power law method, the time-dependent model, the dose to equivalent damage approach, and the simplified method approach. Because of the expected and observed changes in chemistry that occur as aging conditions transition radiation–temperature space, we highlight issues with the time-dependent and simplified method approaches by showing that they do not simulate the chemistry occurring under ambient conditions. The DED approach and a recent modification, the Matched Accelerated Conditions approach, can handle the changes in chemistry for many important cable materials and therefore offer more confident accelerated simulations. Problems with the power law method are then briefly described. Also discussed are the significant issues that occur when trying to simulate the aging of semicrystalline cable materials that show inverse-temperature effects. For these materials, degradation rates under radiation can increase as the aging temperature drops below ∼60 °C, in temperature regions where typical ambient aging conditions occur. A possible approach for dealing with such materials is suggested.

ADVANCES IN TECHNIQUES AND APPLICATIONS OF RUBBER SURFACE GRAFTING MODIFICATION

ABSTRACT To meet the requirement in the application of medical devices, composites, biomaterials, corrosion resistance, and selective adsorptions, rubber surface modification is usually indispensable. Grafting treatment is one of most significate treatment methods. In this paper, we focus on rubber surface grafting modification, including grafting techniques and applications. Different grafting methods—including monomer grafting polymerization and coupling reaction—are covered and compared briefly. The related applications of surface grafting modification techniques, such as improving compatibility of waste rubber as fillers, hydrophobicity and lipophilicity of sponge rubber for oil–water separation, biocompatibility of rubber in the medical field, and forming surface patterns, are demonstrated in detail. The new research directions of surface grafting techniques as well as main challenges in application are also discussed.

ADDITIVE MANUFACTURING AND VULCANIZATION OF CARBON BLACK–FILLED NATURAL RUBBER–BASED COMPONENTS

ABSTRACT Additive manufacturing of thermoplastics or metals is a well-approved sustainable process for obtaining rapidly precise and individual technical components. Except for crosslinked silicone rubber or thermoplastic elastomers, there is no method of additive manufacturing of elastomers. Based on the development of the additive manufacturing of elastomers (AME) process, the material group of rubber-based cured elastomers may gain first access to the process field of three-dimensional (3D) printing. Printing and crosslinking of rubber is separated into two steps. In the first step, printing is realized by extrusion of the rubber by using a twin-screw extruder, which works according to the derived fused-filament-fabrication principle. In the second step, the component is vulcanized in a high-pressure hot-air autoclave. Because of the plastic flow behavior of non–crosslinked rubber materials, a thermoplastic shell is probably needed to maintain the geometry and position of the additively manufactured rubber. In this way, one layer of thermoplastic and one layer of rubber are printed alternatingly until the component is finished. Afterward, the manufactured binary component is placed in an autoclave to obtain the elastomer after vulcanization under a hot-air and high-pressure atmosphere. Then, the thermoplastic shell is removed from the elastomer and can subsequently be recycled. As compared with conventional thermoplastics, the high viscosity of rubber during processing and its instable shape after extrusion are challenging factors in the development of the AME. This contribution will show a modified 3D printer; explain the printing process from the designed component, via shell generation, to the vulcanized component; and show first printed components.

ENTIRE-REGION CONSTITUTIVE RELATION FOR TRELOAR'S DATA

ABSTRACT Hyperelastic materials can experience a large deformation process. A constitutive relation suitable for an entire region from small, moderate, to large deformations is of great importance for practical applications such as fracture problems. Treloar's data are first investigated, and the tension curve is divided into three regimes: small-to-moderate regime, strain-hardening regime, and limiting-chain regime. Next, the modeling theory of hyperelastic materials is introduced, and the tensile behaviors of basic energy functions are analyzed for different deformation regimes. Finally, a successive procedure is suggested to establish an entire-region constitutive relation and then applied to Treloar's data. The present constitutive relation can maintain the initial shear modulus while the experimental data are satisfactorily predicted. The present procedure is simple and feasible and hence applicable to other hyperelastic materials when their entire-region constitutive relations are studied based on experimental data.