Synthesis, Characterization, and Crystal Structure of 3,3,6,6-Tetramethyl-9-(4-Methoxyphenyl)-10-(4-Chlorophenyl)-1,8-Dioxodecahydroacridine Dimethyl Sulfoxide

Abstract C16H11N5O10S, triclinic, P 1 ‾ $P‾{1}$ (no. 2), a = 4.6658(1) Å, b = 12.2129(4) Å, c = 17.0355(5) Å, α = 74.925(2)°, β = 86.398(2)°, γ $\gamma $ = 88.040(2)°, V = 935.31(5) Å3, Z = 2, R gt (F) = 0.0642, wR ref (F 2) = 0.1744, T = 295 K.

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The crystal structure of (Z)-3-hydrazono-5-nitroindolin-2-one – dimethyl sulfoxide (1/1), C8H6N4O3

Zeitschrift für Kristallographie - New Crystal Structures ◽

10.1515/ncrs-2019-0806 ◽

2020 ◽

Vol 235 (2) ◽

pp. 501-502

Author(s):

Abdulrahman M. Al-Obaid ◽

Saeed Ali Syed ◽

Bari Ahmed ◽

Eric C. Hosten

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide

AbstractC8H6N4O3 ⋅ C2H6OS, orthorhombic, Pnma (no. 62), a = 10.4813(5) Å, b = 6.8663(4) Å, c = 17.2605(9) Å, V = 1242.20(11) Å3, Z = 4, Rgt(F) = 0.0506, wRref(F2) = 0.1590, T = 200(2) K.

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Dimer species in dimethyl sulfoxide–water (80∶20 w/w) solution of N,N′-bis(salicylideneimine)-m-phenylenediamine (H2sal-m-phen) and similar Schiff bases with CuII, NiII, CoII and ZnII. Crystal structure of [Co2(sal-m-phen)2]·CHCl3 ‡

Journal of the Chemical Society Dalton Transactions ◽

10.1039/a702151h ◽

1997 ◽

pp. 4327-4334 ◽

Cited By ~ 32

Author(s):

Rita Hernández-Molina ◽

Alfredo Mederos ◽

Pedro Gili ◽

Sixto Domínguez ◽

Francesc Lloret ◽

...

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide ◽

Schiff Bases

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Crystal structure of [di(µ2-cyanido)-dicyanido-bis(dimethyl sulfoxide-κO)- bis(2,2′-(ethane-1,2-diylbis(azanylylidenemethanylylidene))diphenolato-κ4,N,N′,O,O′)- dimanganese(III)-platinum(II)], C40H40Mn2N8O6PtS2

Zeitschrift für Kristallographie - New Crystal Structures ◽

10.1515/ncrs-2021-0026 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Kwang Ha

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide

Abstract C40H40Mn2N8O6PtS2, monoclinic, P21/n (no. 14), a = 10.5707(3) Å, b = 18.5331(5) Å, c = 12.0293(3) Å, β = 114.6276(10)°, V = 2142.26(10) Å3, Z = 2, R gt (F) = 0.0148, wR ref (F 2) = 0.0380, T = 223 K.

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Crystal structure of catena-bis(dimethyl sulfoxide)bis(μ2-thiocyanato)-cadmium(II), C6H12CdN2O2S4

Zeitschrift für Kristallographie - New Crystal Structures ◽

10.1515/ncrs-2000-0148 ◽

2000 ◽

Vol 215 (1) ◽

pp. 91-92 ◽

Cited By ~ 1

Author(s):

X. Q. Wang ◽

W. T. Yu ◽

D. Xu ◽

D. R. Yuan ◽

Μ. K. Lu ◽

...

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide

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Diosgenin hemihydrate

Acta Crystallographica Section E Structure Reports Online ◽

10.1107/s1600536812027912 ◽

2012 ◽

Vol 68 (8) ◽

pp. o2357-o2357 ◽

Cited By ~ 3

Author(s):

María-Guadalupe Hernández Linares ◽

Sylvain Bernès ◽

Marcos Flores-Alamo ◽

Gabriel Guerrero-Luna ◽

Anselmo A. Martínez-Gallegos

Keyword(s):

Crystal Structure ◽

Water Molecule ◽

Dimethyl Sulfoxide ◽

Starting Material ◽

Water Molecules ◽

Asymmetric Unit ◽

Acta Cryst ◽

X Ray ◽

Hydroxy Groups ◽

Hydrogen Bonded

Diosgenin [or (22R,25R)-spirost-5-en-3β-ol] is the starting material of the Marker degradation, a cheap semi-synthesis of progesterone, which has been designated as an International Historic Chemical Landmark. Thus far, a single X-ray structure for diosgenin is known, namely its dimethyl sulfoxide solvate [Zhanget al.(2005).Acta Cryst.E61, o2324–o2325]. We have now determined the structure of the hemihydrate, C27H42O3·0.5H2O. The asymmetric unit contains two diosgenin molecules, with quite similar conformations, and one water molecule. Hydroxy groups in steroids and water molecules form O—H...O hydrogen-bondedR54(10) ring motifs. Fused edge-sharingR(10) rings form a backbone oriented along [100], which aggregates the diosgenin molecules in the crystal structure.

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ChemInform Abstract: URANYL COMPLEXES WITH BIDENTATE DERIVATIVES OF PYRIDINE N-OXIDE. THE CRYSTAL STRUCTURE OF (DIMETHYL SULFOXIDE)BIS(1-OXO-2-THIOPYRIDINATO)DIOXOURANIUM(VI) AND AQUABIS(1,2-DIOXOPYRIDINATO)DIOXOURANIUM(VI) MONOHYDRATE

Chemischer Informationsdienst ◽

10.1002/chin.198341299 ◽

1983 ◽

Vol 14 (41) ◽

Author(s):

U. CASELLATO ◽

P. A. VIGATO ◽

S. TAMBURINI ◽

R. GRAZIANI ◽

M. VIDALI

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide ◽

Uranyl Complexes ◽

Derivatives Of

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The crystal structure and electronic properties of the bis(1,3-dimethyl-5-diazophenyl-6-amino uracilato) copper(II) complex, dimethyl sulfoxide solvate - a new pseudotetrahedral CuN4 complex

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)91061-2 ◽

1990 ◽

Vol 173 (1) ◽

pp. 107-114 ◽

Cited By ~ 13

Author(s):

Veena Ravichandran ◽

K.K. Chacko ◽

A. Aoki ◽

H. Yamazaki ◽

J. Ruiz-Sanchez ◽

...

Keyword(s):

Crystal Structure ◽

Dimethyl Sulfoxide ◽

Electronic Properties

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Effects of solvents on the crystal structure of cross-linked lysozyme crystals

International Journal of Modern Physics B ◽

10.1142/s0217979218400416 ◽

2018 ◽

Vol 32 (19) ◽

pp. 1840041

Author(s):

Yohei Yamada ◽

Shota Toyama ◽

Tomoki Yabutani

Keyword(s):

Crystal Structure ◽

Acetic Acid ◽

Hydrochloric Acid ◽

Dimethyl Sulfoxide ◽

Optical Microscopy ◽

Immersion Test ◽

X Ray ◽

Lattice Constants ◽

X Ray Crystallography ◽

Lysozyme Crystals

The effects of solvents on the structural stability of cross-linked lysozyme crystals were investigated by an immersion test using alkaline (0.1 M ammonia [NH3] and 0.1 M sodium hydroxide [NaOH]), acidic (0.1 M acetic acid [CH3COOH] and 0.1 M hydrochloric acid [HCl]) and organic (50% [v/v] and undiluted ethanol, acetone, 2-propanol and dimethyl sulfoxide [DMSO]) solvents. The morphology and lattice constants were monitored by optical microscopy and X-ray crystallography. The cross-linked crystals exhibited good stability against NH3, CH3COOH, HCl, ethanol, acetone and 2-propanol. However, samples preserved in DMSO and NaOH were severely degraded.

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