Extended angular overlap model in the structure theory of transition metal complexes. Basic principles

2007 ◽  
Vol 33 (8) ◽  
pp. 551-559 ◽  
Author(s):  
Yu. V. Rakitin ◽  
V. T. Kalinnikov ◽  
S. G. Khodasevich ◽  
V. M. Novotortsev
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structure Theory ◽  
Basic Principles ◽  
Angular Overlap Model ◽  
Overlap Model

Transition Metal Complex Catalysed Photo- and Electrochemical (De)hydrogenations Involving C=O- and C=N-Bonds

Synthesis ◽  
2021 ◽  
Author(s):  
Igor Fokin ◽  
Kai-Thorben Kuessner ◽  
Inke Siewert
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Transition Metal Complex ◽  
Basic Principles

Herein, we summarize the photo- and electrochemical protocols for dehydrogenation and hydrogenations involving carbonyl and imine functions. The three basic principles that have been explored to interconvert such moieties with transition metal complexes are discussed in detail and the substrate scope is evaluated. Furthermore, we describe some general thermodynamic and kinetic aspects of such electro- and photochemically driven reactions.

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