The influence of reagent concentration on the kinetics of carbon dioxide-propylene oxide copolymerization in the presence of a cobalt complex

2014 ◽  
Vol 56 (5) ◽  
pp. 547-552 ◽  
Author(s):  
O. M. Chukanova ◽  
E. O. Perepelitsina ◽  
G. P. Belov
Keyword(s):  
Carbon Dioxide ◽  
Propylene Oxide ◽  
Cobalt Complex ◽  
Reagent Concentration ◽  
Kinetics Of

Kinetics of Ternary Copolymerization of Carbon Dioxide with Propylene Oxide, Butene Oxide, and Cyclohexene Oxide

2019 ◽  
Vol 61 (4) ◽  
pp. 395-403 ◽  
Author(s):  
O. M. Chukanova ◽  
K. O. Korenkov ◽  
E. O. Perepelitsina ◽  
N. O. Garifullin ◽  
I. V. Sedov
Keyword(s):  
Carbon Dioxide ◽  
Propylene Oxide ◽  
Cyclohexene Oxide ◽  
Kinetics Of

The kinetics of carbon dioxide and propylene oxide copolymerization catalyzed by binary catalyst system

2015 ◽  
Vol 57 (3) ◽  
pp. 224-227 ◽  
Author(s):  
O. M. Chukanova ◽  
E. V. Bukhovets ◽  
E. O. Perepelitsina ◽  
G. P. Belov
Keyword(s):  
Carbon Dioxide ◽  
Propylene Oxide ◽  
Catalyst System ◽  
Binary Catalyst ◽  
Kinetics Of

scholarly journals Salen cobalt complex catalyzes the copolymerization of carbon dioxide and propylene oxide with high activity

2021 ◽  
Vol 844 (1) ◽  
pp. 012004
Author(s):  
Wen-Zhen Wang ◽  
Yi-Le Zhang ◽  
Jun Shi ◽  
Li Wang ◽  
Xin-Gang Jia ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Activity ◽  
Propylene Oxide ◽  
Cobalt Complex

Kinetics of Carbon Dioxide Terpolymerization with Propylene Oxide and Hexene Oxide

2020 ◽  
Vol 61 (4) ◽  
pp. 569-574
Author(s):  
O. M. Chukanova ◽  
K. O. Korenkov ◽  
N. O. Garifullin ◽  
O. G. Sheverdenkina ◽  
I. V. Sedov
Keyword(s):  
Carbon Dioxide ◽  
Propylene Oxide ◽  
Kinetics Of

Kinetics of temperature-programmed reactivation of a hydrodesulphurization catalyst

1983 ◽  
Vol 48 (12) ◽  
pp. 3340-3355 ◽  
Author(s):  
Pavel Fott ◽  
Pavel Šebesta
Keyword(s):  
Carbon Dioxide ◽  
Thermal Analysis ◽  
Differential Thermal Analysis ◽  
Thin Layer ◽  
Kinetic Parameters ◽  
Diffusion Region ◽  
Reaction Heat ◽  
Gaseous Products ◽  
Temperature Programmed ◽  
Kinetics Of

The kinetic parameters of reactivation of a carbonized hydrodesulphurization (HDS) catalyst by air were evaluated from combined thermogravimetric (TG) and differential thermal analysis (DTA) data. In addition, the gaseous products leaving a temperature-programmed reactor with a thin layer of catalyst were analyzed chromatographically. Two exothermic processes were found to take part in the reactivation, and their kinetics were described by 1st order equations. In the first process (180-400 °C), sulphur in Co and Mo sulphides is oxidized to sulphur dioxide; in the second process (300-540 °C), in which the essential portion of heat is produced, the deposited carbon is oxidized to give predominantly carbon dioxide. If the reaction heat is not removed efficiently enough, ignition of the catalyst takes place, which is associated with a transition to the diffusion region. The application of the obtained kinetic parameters to modelling a temperature-programmed reactivation is illustrated on the case of a single particle.

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