Optimization of the conditions for preparation of silyl derivatives of phenylcarboxylic acids in diethyl and methyl tert-butyl ethers

2015 ◽  
Vol 51 (6) ◽  
pp. 1076-1079 ◽  
Author(s):  
A. K. Pautova ◽  
A. I. Revelsky
2007 ◽  
Vol 60 (1-2) ◽  
pp. 193-196 ◽  
Author(s):  
Abdelwaheb Hamdi ◽  
Rym Abidi ◽  
Jacques Vicens

1999 ◽  
Vol 35 (9) ◽  
pp. 1052-1058 ◽  
Author(s):  
E. Abele ◽  
K. Rubina ◽  
R. Abele ◽  
I. Sleiksha ◽  
E. Lukevics

1967 ◽  
pp. 869 ◽  
Author(s):  
J. Chatt ◽  
C. Eaborn ◽  
S. Ibekwe ◽  
P. N. Kapoor

2006 ◽  
Vol 76 (11) ◽  
pp. 1753-1756 ◽  
Author(s):  
A. A. Prishchenko ◽  
M. V. Livantsov ◽  
O. P. Novikova ◽  
L. I. Livantsova ◽  
D. B. Shpakovskii ◽  
...  
Keyword(s):  

2013 ◽  
Vol 87 (8) ◽  
pp. 1253-1258
Author(s):  
Yu. P. Pavlovskii ◽  
N. S. Kachurina ◽  
S. I. Gerasimchuk ◽  
Yu. Ya. Van-Chin-Syan

2006 ◽  
Vol 84 (10) ◽  
pp. 1250-1253 ◽  
Author(s):  
Mee-Kyung Chung ◽  
Paul Fancy ◽  
Jeffrey M Stryker

The direct synthesis of sterically hindered, partially etherified derivatives of tetrakis(2-hydroxyphenyl)ethene is reported by using the McMurry reductive olefination reaction on a range of differentially substituted 2,2′-dialkoxy benzophenone substrates. Three orthogonal protection strategies are demonstrated, incorporating β-silylethyl, 3-butenyl, and tert-butyl protecting groups, respectively, into the starting benzophenones. The latter proved most efficient, with both the McMurry coupling and deprotection steps occurring concomitantly under the McMurry conditions to directly yield the desired bis(2-hydroxyphenyl)-bis(2-methoxyphenyl)ethene as a 1:1 mixture of E- and Z-diastereoisomers.Key words: preorganized polyaryloxide ligands, McMurry olefination, titanium trichloride, supramolecular chemistry, tetrakis(2-hydroxyphenyl)ethene, 2,2′-disubstituted benzophenone.


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