Oxidation of benzaldehyde by dioxygen. Photoinitiated reaction

The photoinitiated oxidation of benzaldehyde is catalyzed by traces of transition metal ions. The photocatalytic effects of transition metals are explained in terms of the formation of their unstable oxidation states which act as catalysts of the thermal oxidation. The reaction catalyzed by Fe(II) and Fe(III) ions is discussed in detail.

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Bond-length distributions for ions bonded to oxygen: Metalloids and post-transition metals

10.26434/chemrxiv.5410921.v2 ◽

2017 ◽

Cited By ~ 1

Author(s):

Olivier Charles Gagné ◽

Frank Christopher Hawthorne

Keyword(s):

Transition Metal ◽

Transition Metals ◽

Metal Ions ◽

Bond Length ◽

Lone Pair ◽

Transition Metal Ions ◽

Oxygen Lone Pair

Bond-length distributions are examined for thirty-three configurations of the metalloid ions and fifty-six configurations of the post-transition-metal ions bonded to oxygen. Lone-pair stereoactivity is discussed.

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Bond-length distributions for ions bonded to oxygen: Metalloids and post-transition metals

10.26434/chemrxiv.5410921 ◽

2017 ◽

Cited By ~ 1

Author(s):

Olivier Charles Gagné ◽

Frank Christopher Hawthorne

Keyword(s):

Transition Metal ◽

Transition Metals ◽

Metal Ions ◽

Bond Length ◽

Lone Pair ◽

Transition Metal Ions ◽

Oxygen Lone Pair

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ChemInform Abstract: On Matrix Stabilization of d- and f-Transition Metal Ions in Unstable Oxidation States

ChemInform ◽

10.1002/chin.200925209 ◽

2009 ◽

Vol 40 (25) ◽

Author(s):

Yu. M. Kiselev

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Transition Metal Ions ◽

Oxidation States ◽

Matrix Stabilization

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Transition-metal ions in borate glasses: Investigation of the electronic structure of linear polyborates, borate clusters and transition metals in borates

Journal of Non-Crystalline Solids ◽

10.1016/0022-3093(77)90100-4 ◽

1977 ◽

Vol 24 (3) ◽

pp. 313-338 ◽

Cited By ~ 15

Author(s):

D.R. Armstrong ◽

R. Fortune ◽

P.G. Perkins

Keyword(s):

Electronic Structure ◽

Transition Metal ◽

Transition Metals ◽

Metal Ions ◽

Transition Metal Ions ◽

Borate Glasses

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ChemInform Abstract: TRANSITION METAL IONS IN HIGH FORMAL OXIDATION STATES. STRUCTURAL CHARACTERIZATION OF THE NICKEL AND COPPER COMPLEXES OF THE 1,1-DICARBOETHOXY-2,2-ETHYLENEDITHIOLATE LIGAND

Chemischer Informationsdienst ◽

10.1002/chin.197644056 ◽

1976 ◽

Vol 7 (44) ◽

pp. no-no

Author(s):

D. COUCOUVANIS ◽

F. J. HOLLANDER ◽

M. L. CAFFERY

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Structural Characterization ◽

Copper Complexes ◽

Transition Metal Ions ◽

Oxidation States

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Correlation between oxidation states of transition metal ions and variation of the coercivity in mixed-valence defect spinel ferrites

Solid State Ionics ◽

10.1016/s0167-2738(97)00142-2 ◽

1997 ◽

Vol 101-103 (1-2) ◽

pp. 457-463 ◽

Cited By ~ 9

Author(s):

E Kester

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Mixed Valence ◽

Transition Metal Ions ◽

Spinel Ferrites ◽

Oxidation States

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Assessment of minimal active space CASSCF-SO methods for calculation of atomic Slater-Condon and spin-orbit coupling parameters in d- and f-block ions

Dalton Transactions ◽

10.1039/d1dt02346b ◽

2021 ◽

Author(s):

Alvin J Walisinghe ◽

Nicholas F Chilton

Keyword(s):

Transition Metal ◽

Metal Ions ◽

Transition Metal Ions ◽

Coupling Constants ◽

Oxidation States ◽

Spin Orbit Coupling ◽

Spin Orbit ◽

Complete Active Space ◽

Active Space ◽

Coupling Parameters

Slater-Condon parameters and the spin-orbit (SO) coupling constants for various oxidation states of transition metal ions (3d/4d/5d) and trivalent f-block ions were calculated using minimal active space complete active space...

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