CONDUCTANCES OF DILUTE SOLUTIONS OF POTASSIUM IODATE IN WATER AND WATER–DIOXANE MIXTURES AT 25 °C

1959 ◽  
Vol 37 (11) ◽  
pp. 1888-1895 ◽  
Author(s):  
E. Bock
Keyword(s):  
Dielectric Constant ◽  
Association Constants ◽  
Potassium Iodate ◽  
Dilute Solutions

Conductances of dilute solutions of potassium iodate in water and water–dioxane solutions, extending over the dielectric constant range from D = 78.54 to D = 29.71, have been measured over the concentration range from zero up to Ka < 0.2 at 25.00 °C. By applying the Fuoss–Onsager treatment to the data obtained, the association constants for the electrolyte in the various solvents, as well as å, the distance of closest approach of the ions, have been determined.

The dispersion of the dielectric constant of some dilute solutions of polar compounds in non-polar solvents

1949 ◽  
Author(s):  
A. D. Franklin ◽  
W. M. Heston ◽  
E. J. Hennelly ◽  
C. P. Smyth
Keyword(s):  
Dielectric Constant ◽  
Polar Compounds ◽  
Dilute Solutions ◽  
Polar Solvents

THE LIMITING CONDUCTANCE OF AQUEOUS SOLUTIONS OF POTASSIUM IODATE, POTASSIUM CHLORATE, AND SILVER NITRATE AT 35.00 °C

1959 ◽  
Vol 37 (5) ◽  
pp. 889-892 ◽  
Author(s):  
E. Bock ◽  
A. N. Campbell
Keyword(s):  
Aqueous Solutions ◽  
Silver Nitrate ◽  
Association Constants ◽  
Potassium Chlorate ◽  
Potassium Iodate ◽  
Extrapolation Procedure ◽  
Limiting Equivalent Conductances

Measurements have been made of the equivalent conductances of aqueous solutions of potassium iodate, potassium chlorate, and silver nitrate at 35.00 °C at concentrations ranging from 0.8 × 10−4 to 16×10−4 N. From these, the limiting equivalent conductances and association constants A as obtained by the use of the Fuoss–Shedlovsky extrapolation procedure were found to be at 35.0 °C:[Formula: see text]

A Conductance Investigation of Sulfamic Acid in Aqueous Solutions of Methanol, Ethanol and Isopropanol at 25 °C

1992 ◽  
Vol 57 (8) ◽  
pp. 1613-1620 ◽  
Author(s):  
Antonis Avranas ◽  
Vasiliki Terzoglou ◽  
Nikos Papadopoulos
Keyword(s):  
Experimental Data ◽  
Dielectric Constant ◽  
Aqueous Solutions ◽  
Association Constant ◽  
Sulfamic Acid ◽  
Dilute Solutions ◽  
Alcohol Mixture ◽  
Water Alcohol

The conductance of dilute solutions of sulfamic acid in water-methanol, water-ethanol and water-isopropanol mixture were measured at 25 °C. The experimental data were processed using the Lee and Wheaton equation to evaluate the limiting conductance Λ0 and association constant Ka. The lowest dielectric constant for each type of water-alcohol mixture was about 20.

scholarly journals Effect of Dielectric Constant of Medium on Conductance for Trimethylsulfonium Halides in Normal and Branched Alcohols

2019 ◽  
Vol 4 (7) ◽  
pp. 18-20
Author(s):  
Nasr H. El-Hammamy ◽  
Marwa A. Daghash ◽  
Aida I. Kawana
Keyword(s):  
Dielectric Constant ◽  
Association Constant ◽  
Infinite Dilution ◽  
Association Constants ◽  
Equivalent Conductance ◽  
Branched Alcohols

The conductance parameters, Λo (equivalent conductance at infinite dilution) and KA (association constant) for trimethylsulfonium halides (Bromide and Iodide) in methanol, ethanol, n-propanol, 2-propanol and n-butanol have been evaluated at 25°C from the conductance measurements. The values of Λo for different salts decrease with decreasing dielectric constant of medium (D) with some variations and are in the order of MeOH > EtOH > n-PrOH > 2-PrOH > n-BuOH. The association constants of the same salts in different alcohols increase with decreasing dielectric constant of medium and are in the order of n-BuOH > 2-PrOH > n-PrOH > EtOH > MeOH.

On the dielectric constant of dilute solutions of polar molecules in non-polar solvents

1975 ◽  
Vol 61 (1) ◽  
pp. 324-335
Author(s):  
André G. Bellemans ◽  
M. Plaitin
Keyword(s):  
Dielectric Constant ◽  
Polar Molecules ◽  
Dilute Solutions ◽  
Polar Solvents

Theory of the Dielectric Constant of Imperfect Gases and Dilute Solutions

1958 ◽  
Vol 28 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Terrell L. Hill
Keyword(s):  
Dielectric Constant ◽  
Dilute Solutions

Theory of the Dielectric Constant of Dilute Solutions. II

1959 ◽  
Vol 30 (4) ◽  
pp. 1114-1114 ◽  
Author(s):  
Terrell L. Hill
Keyword(s):  
Dielectric Constant ◽  
Dilute Solutions

Dielectric constant meter for dilute solutions

1953 ◽  
Vol 49 ◽  
pp. 92
Author(s):  
Andrew W. Henderson ◽  
Duncan Taylor
Keyword(s):  
Dielectric Constant ◽  
Dilute Solutions
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