Geochemistry and Petrogenetic Relationships Between Pegmatites and Host Rocks in the Keffi Area, North Central, Nigeria

Keffi pegmatites area which contains numerous mineralised and non-mineralised pegmatites lie between the Wamba pegmatite field to the NE and Nasarawa pegmatite field to the SW on the North Central Pegmatite belt of Nigeria. In Keffi area exploitation of deposits is currently being done by small scale miners, whose activities are haphazard and uncoordinated, because of that information on the geology and petrology that will enable a systematic study of the pegmatites in the area is scanty. Systematic geochemical investigations of the pegmatites and surrounding host rocks aimed at establishing petrogenetic relationships amongst the various rock types in the area were conducted. Major, trace and REE investigations of the pegmatites and associated granitoids have indicated petrogenetic relationships amongst the pegmatites and between the pegmatites and surrounding granitoids of Keffi area. Also, the variation diagram of major, trace and REE in whole rocks and K-feldspar samples show patterns which categorised the pegmatites of Keffi area into; (1) Non-mineralised, (2) intermediate and (3) mineralised pegmatites. It was also deduced from the geochemical characteristics (variation diagrams in major and trace element, REE geochemistry and tectonic environment classification) that a genetic model based on the evolution of melt by partial melting of metasedimentary protolith during ultrametamorphic and deformational activities (anatexis) is proposed for the granite-pegmatite system of Keffi area. This information will be useful as guide for fruitful exploration of the pegmatites and serves as model for the exploitation of pegmatite veins in similar geologic settings.

Optimal Sliding Mode Control of Permanent Magnet Direct Drive Linear Generator for Grid-Connected Wave Energy Conversion

the key goal of this article is on the design and optimum sliding mode control for Grid-Connected direct drive extraction method of ocean wave energy by Multi-Objective Particle Swarm Optimization (MOPSO). A Linear Permanent Magnet Generator simulates the ocean wave energy extraction system, driven by an Archimedes Wave Swing. Uncontrolled three-phase rectifiers, a three-level buck-boost converter and 3 level neutral point clamped inverter are planned grid integration of Wave Energy Conversion device. The technique monitors the three-level buck-boost converter service cycle linked to the PMLG output terminals and decides the optimum switching sequence of 3 level neutral point clamped inverter to enable the grid relation. Simulations using Matlab/Simulink were carried out to test working of the wave energy converter after the suggested optimal control method was applied under various operating settings. Various simulation test results indicate that the proposed optimum control system is tested in both normal and irregular ocean waves. And it has been shown that the control method of the MOPSO sliding mode is ideal for maximizing energy transfer efficiency. Better voltage management at the DC-link and for achieving greater controllability spectrum was accomplished by the proposed Duty-ratio optimal control system.

Geochemistry and Mineralization of Some Selected Pegmatite Deposits in Panda North Central, Nigeria

Pegmatite constitutes an important lithologic unit in the Precambrian Basement Complex of Panda north central Nigeria. The primary aim of this study is to present a geochemical data of various rock types in the area especially pegmatite in order to determine their geochemical classification and mineralization potential of some selected pegmatite deposits in the area. Geochemical analysis reveals that the pegmatite samples have high SiO2 content; 73.8-94.8 wt%, low Na2O/K2O ratio suggesting they are strongly peralkaline and peraluminous, indicating that the pegmatite may have formed from mixed plutonic sources. The discrimination diagram of TiO2 versus SiO2 shows that the samples plotted on both igneous and sedimentary field, but majorly on the igneous field which is an implication that substantial material may have been generated from igneous sources. Also the plotting of the pegmatite samples in both the tholeiitic and calc-alkaline fields shows that the magma from which the rock was formed was not totally restricted in occurrence only to subduction related environment but also from the oceanic crust of calc-alkaline environments. This is further confirmed by discrimination diagrams plot of TiO2-K2O-P2O which indicates that substantial samples plotted fall within the continental crust. High potash content alkalies with relative Fe-enrichment and silica suggest the plutonic generation of magma and the development of the rocks in both the oceanic and continental crust. Major elements analysis of both the granitic rock aplite and biotite gneiss shows moderately high silica values. These values reflect the geochemical characteristic of crystalline rocks. The pegmatite of the study area exhibits low contents of Nb, Ta, Ga, Rb and Sn which are the major mineralization indices for pegmatite bodies. In classifying the pegmatites, rare metal indicative elements were used to discriminate the barren ones from the mineralized. A plot of Ta-Ga reveals that all the samples plotted are below the boundary of mineralization line, suggesting all the pegmatite samples in the study area to be barren in term of rare earth metals and can be compared to other pegmatite bodies in Nigeria and around the world.

Performance Analysis of a Dual-Fuel Sugar Based Solid Rocket Propellant

The effects of dual-fuel on improving the ballistic efficiency of a low energy sugar-based solid rocket propellant were investigated in this paper. This was achieved by establishing a threshold proportion of sucrose to sorbitol that provided the highest ballistic efficiency, using a beam load cell (model single-point 2,000 kg linearly defined by 0-20 kN force, with ±.005 percent precision). Seven different propellant formulations were prepared, loaded into the rocket motor and tested for performance. The major performance parameters of interest were the thrust, total impulse, burn time, delivered specific impulse, delivered characteristic velocity, and the chamber pressure. The formulations tested were potassium nitrate–sucrose propellant (65% KNO3 and 35% sucrose (C12H22O11)) (KNSU); potassium nitrate-sorbitol propellant (65% KNO3 and 35% sorbitol (C6H14O6)) (KNSB); modified potassium nitrate-sucrose propellant (65% KNO3, 32% sucrose (C12H22O11)), and 3% carbon (C) (MODKNSU); potassium nitrate-sucrose-sorbitol propellant (65% KNO3, 25% sucrose (C12H22O11)), and 10% sorbitol (C6H14O6) (KNERK); potassium nitrate-sucrose-sorbitol-carbon propellant (65% KNO3, 24% sucrose (C12H22O11), 10% sorbitol (C6H14O6), and 1% carbon (C)) (MODKNERK); and finally a propellant made from KNO3, sucrose (C12H22O11), sorbitol (C6H14O6), carbon (C) and iron II oxide(Fe2O3) combinations in 65, 30, 3, 1, 1% proportion respectively. The novel result obtained from these experiments was applied to boost the performance of a KNSB rocket propellant motor during a rocket launch experiment. Both static and dynamic rocket motor internal ballistic parameters were then compared. The measured delivered motor average thrust and the effective propellant burn times were recorded as: (164.15N, 3.97s); (102.95N, 6.53s); (65.66N, 9.38s); (79.09N, 3.77s); (243.98N, 3.77s) and (92.6N, 5.89s) respectively. The MODKNERK, was established to produce a most efficient motor and with the full delivery of its ballistic energy. It was also established, that the ballistic and rocket motor efficiency of a lower energy rocket motor can be improved by starting the ignition of such motor with fast burning dual-fuel rocket propellant (MODKNERK).

Investigation of the Ultraviolet Irradiation on Blend Films of PS/PCL

In this work, an investigation was carried out on the effect of ultraviolet light on different films. Polystyrene (PS), poly (caprolactone) (PCL), and blended films of PS/PCL were produced. Ethyl acetate (AE) was used as a solvent, and PS and PCL solutions were prepared by dissolving 250 mg in 2.5mL of AE under mechanical stirring at room temperature. The blended solutions of PS/PCL (PS:PCL) were prepared with different mass proportions, such as 90:10, 80:20, 70:30, and 60:40 into 2.5 mL of EA. The solutions were dripped with 500 µL on a glass substrate, and the films were produced with mechanical rotation of N=2000 RPM for 15 seconds using a Spin coater. The films were submitted to ultraviolet light for t=60 minutes and morphologically analyzed by optical microscopy, chemically by IR spectroscopy, and superficially by contact angle and wettability; this last analysis also investigated the effect of ultraviolet light at t=0, t=30, and t=60 minutes. The exposure of ultraviolet light on the films affected its morphologies. IR spectra showed that the photodegradation increased for larger PCL amounts into the blend. The contact angle measurements showed that after exposure to ultraviolet light, the hydrophobicity of the films increased. Therefore, the presence of PCL in the polymer mixture promoted the photodegradation of the PS/PCL films, making it attractive for developing new packaging.

Features of the Electrochemical Deposition of Films from a Triple System of CoNiFe

The nature of phenomena that occurs in the electrolyte during the electrochemical deposition of CoNiFe films and the mechanism leading to the difference in the relative content of elements in the electrolyte and film was clarified. This clarification was obtained with the help of a spectrophotometric study of chloride electrolytes and the electrochemical deposition of CoNiFe films at 70 °C. An experimental study of the absorption spectra and the pH values of the FeCl2, NiCl2 and CoCl2 salt solutions at concentrations of 0.005 to 1 mol/l showed the complex nature of the ion-formation balance in single-component and mixed solutions and the dependence of ion formation on acidic and alkaline additives. The deposited CoNiFe film was made from a chloride electrolyte with a component content ratio of 1:1:1 at both high (0.5 mol/l) and low (0.006 mol\l) concentrations of each component. The content of each component in the film after the electrochemical deposition of the three component solution (FeCl2, CoCl2, and NiCl2 at equal concentrations) did not correspond to the composition of the electrolyte. The mechanism for the abnormal deposition of Co, Fe, Ni occurred due to the incomplete ionization of atoms and the differences in the mobility of ions. The magnetic susceptibility of the films formed in the triple CoNiFe system was higher than that of a permalloy. Therefore, the triple system shows promise for use in magnetic field converters.

Prediction of Fracture Pressure in Niger Delta Deep Offshore

During drilling operations, it is essential to keep the wellbore pressure within the maximum value of the fracture pressure and minimum value of the pore pressure of the formation. To handle this challenge, the fracture pressure of the formation must be known as it is significant to determining the mud window design. This study developed a correlation that could predict the formation fracture pressure in the Niger Delta deep offshore field. Two different fields were considered for this model named Field 1 and 2. From these fields, fracture pressure data were gotten from 21 wells during leak off test (LOT) at different casing shoe depths. While carrying-out the analysis of data, assumptions were made that the formations throughout the Niger Delta basin obeys the principle of horizontality. Also, that the fracture pressure at same depth is uniform with the pressure at other location in the Delta. Scatter plot was used as the tool for the data analysis. A line of best fit was drawn to arrive at the correlation. This correlation has an R2 coefficient values of 0.9969. In conclusion, the correlation gotten from this study for predicting fracture pressure has shown to align with some data sets from the Niger Delta fields with very little variation. This can be used for planning of further drilling operations in the Niger Delta to make it easier, faster and more economical.

Development of a YAMUGAG-20 Wireless Exploder for Safe Disposal of Military and Civil Explosives

YAMUGAG-20 Exploder is a Radio Frequency (RF)-based wireless exploder system designed and constructed specially for the Nigerian Air Force (NAF) to overcome the challenges associated with the existing wired exploders used for the disposal of unserviceable ordnances. The Exploder system has three main parts namely, the master transmitter unit, the master receiver/slave transmitter unit, and the slave receiver unit. Each of these units is made up of transceiver module, microcomputer and power source. The microcomputers were programmed using C and C++ programming language of the Integrated Development Environment (IDE) software. The exploder is portable and easy to operate. For a typical demolition exercise, the operation of the exploder is such that signals are relayed from the master transmitter unit to the master receiver/slave transmitter unit onto the slave receiver unit to initiate an electric detonator leading to the detonation of the unserviceable ordnances. Functionality, range, power consumption, and system reliability tests were conducted on the exploder to establish its performance and efficiency. The results obtained from the tests indicated that the exploder transmitting at a frequency of 2.4GHz performed satisfactorily up to a range of 1000 meters. Therefore, the exploder has the potential of not only meeting the demolition demands of the NAF but can also be applied for other nonmilitary purposes like mining and related activities.

Application of Augmented Water Flooding Using Ultrasound Energy to Improve Oil Recovery

The application of ultrasound energy in improving oil recovery is an emerging technique, it has been tested in laboratories and some field applications in different parts of the world. In this study, Nigerian crude oil of 4.21 cSt viscosity and sandstone rock samples were tested using a designed and constructed experimental rig. The rig is an analogue of a standard core flooding set up and works on the principle of fluid flow in porous media. Furthermore, a modeled equation was developed to better understand the effects of power and time on the volume of oil recovered at a constant ultrasound frequency. Results obtained show a positive impact in the recovery of residual oil during waterflooding with the assisted ultrasound energy. About 2-fold increase in the recovery of oil was observed when the ultrasound energy was applied to augment the waterflooding process. Model equations developed were found to be adequate because the adjusted and predicted R-squared values show reasonable agreement (R-adjusted = 0.9993, R-Predicted = 0.9974).

Problems in Electric Systems Caused by Harmonics and Solution Proposals

Together with globalization, factories, companies and even countries can survive by competing with their rivals. Nowadays, technological superiority is one of the most important factors determining competitive power. This situation causes the result of rapid change and development of technology. Due to improvement in technology, humanity dependence on electricity is increasing day by day. Many new devices get in our lives, and both the continuity and quality of electricity comes across as an important issue. Different researches are carried out to make the energy more qualified and efficient. In terms of the stability of the used electrical devices, it is important to keep the harmonic amount in electrical energy under a certain value. Besides this, these unwanted harmonics cause additional energy losses in the energy system and negatively affect energy efficiency, which is an economically important problem. In this exercise, the problems in electrical systems, the damages in electrical devices caused by harmonics have been researched and various solution suggestions have been developed for this problem.