Application of Paramagnetic Shift Reagents in Nuclear Magnetic Resonance Studies of Complex Alcohols and Amines

1971 ◽  
Vol 49 (2) ◽  
pp. 211-216 ◽  
Author(s):  
Elaine Gillies ◽  
W. A. Szarek ◽  
M. C. Baird
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Ethyl Acetoacetate ◽  
Paramagnetic Shift ◽  
Magnetic Resonance Studies ◽  
Nuclear Magnetic Resonance Spectra ◽  
Shift Reagents ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

The effects of Co(acetylacetonate)2, Ni(acetylacetonate)2, and Cu(ethyl acetoacetate)2 on the nuclear magnetic resonance spectra of a variety of alcohols and amines have been studied. Changes are produced in the spectra, which are useful for assigning the signals.

Use of paramagnetic shift reagents for simplification of nuclear magnetic resonance spectra of organic nitriles

1973 ◽  
Vol 45 (8) ◽  
pp. 1410-1416 ◽  
Author(s):  
Judy A. Young ◽  
Jeanette G. Grasselli ◽  
William M. Ritchey
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Paramagnetic Shift ◽  
Nuclear Magnetic Resonance Spectra ◽  
Shift Reagents ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

Fluorine magnetic resonance studies. III. Fluorine-fluorine coupling over six and seven bonds in fluorostyrenes

1977 ◽  
Vol 30 (3) ◽  
pp. 543 ◽  
Author(s):  
DA Burgess ◽  
ID Rae ◽  
JD Snell
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Aromatic Ring ◽  
Long Range ◽  
Magnetic Resonance Studies ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

The 19F nuclear magnetic resonance spectra of β,β-difluorostyrenes and 1-difluoromethyleneindans bearing fluorine substituents in the aromatic ring have been recorded and the long-range couplings 6JF,F and 7JF,F are discussed. In each compound the larger couplings are to the olefinic fluorine trans to the aromatic ring. The couplings are maximum in the planar indans, reducing to unobservable values when non-planarity is achieved in suitably substituted styrenes. The allylic coupling 4JH,F involving olefinic fluorines shows only slight stereochemical dependence.

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