The Oxidation of 2-Propanol by Ruthenium Tetroxide
1972 ◽
Vol 50
(13)
◽
pp. 2000-2009
◽
Keyword(s):
The kinetics of the oxidation of 2-propanol by ruthenium tetroxide in aqueous perchloric acid solutions have been investigated. The results indicate that the two mechanisms pertain; at moderate acidities (1–6.5 M HClO4) the rate determining step involves hydride abstraction while at very high acid concentrations the rate determining step becomes carbonium ion formation.
1972 ◽
Vol 50
(19)
◽
pp. 3129-3134
◽
Keyword(s):
2018 ◽
Vol 54
(5)
◽
pp. 815-827
◽
Keyword(s):