Thermodynamics of binary mixtures of 1,2-dichloroethane with aromatic hydrocarbons

1980 ◽  
Vol 58 (18) ◽  
pp. 1902-1905 ◽  
Author(s):  
Ram K. Nigam ◽  
Prem P. Singh ◽  
Krishan C. Singh ◽  
Mohan Singh ◽  
Ruchi Mishra

Molar excess volumes, VE at 298.15 and 308.15 K, molar excess enthalpies HE at 308.15 K, and total vapour pressure at 298.15 and 308.15 K. have been measured for binary mixtures of 1,2-dichloroethane with aromatic hydrocarbons. The VE and HE data for an equimolar mixture at 308.15 K only have been utilized to predict VE, HE, and TSE values (using Sanchez and Lacombe theory) for these mixtures as a function of temperature and composition. The agreement between the predicted and the corresponding experimental values is good so far as VE and HE data are concerned but the same is not true of the TSE values.


1973 ◽  
Vol 26 (2) ◽  
pp. 431 ◽  
Author(s):  
S Ruenkrairergsa ◽  
NF Pasco ◽  
DV Fenby

The molar excess enthalpies and molar excess volumes of carbon tetra- chloride + hexafluorobenzene have been measured at 298.15 K and 308.15 K. The values for the equimolar mixture at 298 15 K are 490 J mol-1 and 0.875 cm3 mol-1 respectively. The results are compared with the values for other liquid mixtures containing a fluorocarbon as one component, and discussed in terms of solubility parameter theory.



1997 ◽  
Vol 75 (12) ◽  
pp. 1896-1904 ◽  
Author(s):  
V.K. Sharma ◽  
Khem Chand Kalra ◽  
A. Katoch

Molar excess volumes, [Formula: see text], and molar excess enthalpies, [Formula: see text], of nitrobenzene (i) + benzene (j) + cyclohexane (k), nitrobenzene (i) + benzene (j) + n-hexane (k), and nitrobenzene (i) + benzene (j) + n-heptane (k) ternary mixtures have been determined dilatometrically and calorimetrically as a function of composition at 298.15 K. The data have been analyzed in terms of (i) the graph-theoretical approach and (ii) Flory's Theory. It has been observed that [Formula: see text], data calculated by graph theoretical as well as Flory's approach compare well with their corresponding experimental values. Keywords: molar excess volumes, molar excess enthalpies, specific interactions, molar volume interaction parameter, molar interaction enthalpy parameter.





2005 ◽  
Vol 235 (1) ◽  
pp. 42-49 ◽  
Author(s):  
Sanjeev Maken ◽  
Bal Raj Deshwal ◽  
Renu Chadha ◽  
Anu ◽  
Krishan Chander Singh ◽  
...  




1990 ◽  
Vol 55 (10) ◽  
pp. 2395-2403 ◽  
Author(s):  
Kamila Chýlková ◽  
Ivona Malijevská

Densities at 20 °C and molar excess volumes calculated from them are reported in the work for the mixtures of the substances: propionic acid-n-heptane, propionic acid-benzene, trifluoroacetic acid-benzene, propionic acid-cyclohexane, acetic acid-cyclohexane, acetic acid-trifluoroacetic acid, acetic acid-propionic acid, and propionic acid-trifluoroacetic acid. For the last system mentioned, a strange dependence of excess volume on composition was found which is noted for three local extremes. The dependences of excess volume on composition are correlated by the Redlich-Kister polynomial.



1993 ◽  
Vol 22 (2) ◽  
pp. 183-189 ◽  
Author(s):  
Homendra Naorem ◽  
Sushil K. Suri


1984 ◽  
Vol 16 (1) ◽  
pp. 25-39 ◽  
Author(s):  
R.K. Nigam ◽  
P.P. Singh ◽  
Sadhna Aggarwal ◽  
S.P. Sharma


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