VACUUM ULTRAVIOLET ABSORPTION SPECTRA OF SOLID HYDROGEN HALIDES

Absorption spectra of solid HCl, HBr and HI films deposited on LiF single crystals cooled at 103–104 K and those annealed have been obtained in the 4–11.5 eV region. The first peaks found around the absorption edges correspond to the first bands (dissociative) in isolated molecules, so that they are regarded as Frenkel exciton peaks. The spectral feature of as-deposited films changed after annealing irreversibly, which suggests the structural transition from an amorphous phase to a crystalline phase in HCl and HBr. In HI, it was revealed that the first band in the gaseous phase consists of three components. The broad structures found above the first peaks do not resemble the structures of the isolated molecules in the same energy region which consist of many lines. The band structures of solid hydrogen halides seem to resemble those of sodium halide crystals and solid rare gases.

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Experimental evidence for trapped exciton states in liquid rare gases

Proceedings of the Royal Society of London Series A - Mathematical and Physical Sciences ◽

10.1098/rspa.1970.0106 ◽

1970 ◽

Vol 317 (1528) ◽

pp. 113-131 ◽

Cited By ~ 63

Keyword(s):

Experimental Evidence ◽

Absorption Spectra ◽

Disordered Systems ◽

Vacuum Ultraviolet ◽

Solid Phase ◽

Liquid System ◽

Rare Gases ◽

Line Broadening ◽

Absorption Bands ◽

Additional Line

In connexion with studies of the electronic structure of disordered systems, we enquire whether there exist exciton states in simple liquids. We report the results of a vacuum ultraviolet spectroscopic study of liquid argon and of liquid krypton doped with xenon. Experimental evidence was obtained for Wannier-Mott type impurity states in liquids which have no parentage in the excited states of the isolated atoms constituting the dense fluid. The absorption spectra of the doped liquid rare gases were monitored in the region 160 to 120 nm. The following experimental results are reported: (a) In the Xe/Ar liquid two absorption bands corresponding to the 1 S 0 → 3 P 1 and to the 1 S 0 → 1 P 1 transitions (or alternatively to the n = 1 Wannier states) were identified at 141 nm (8.80eV)† and at 123nm (10.1 eV). An additional line was observed at 127 nm (9.76eV). (b) In the Xe/Kr liquid three absorption bands were observed at 144.5 nm (8.59 eV), 125.5 nm (9.89 eV) and 129 nm (9.6 eV). (c) The absorption spectra of the doped liquids were compared with the spectra of 1 cm thick doped solid rare-gas crystals. From these results we conclude that: (a) The 127 nm (9.76 eV) band in the Xe/Ar liquid system and the 129 nm (9.61 eV) band in the Xe/Kr liquid system cannot be attributed to a perturbed ‘atomic’ state and are assigned to the n = 2 Wannier state in the liquid. (b) Line broadening of exciton states in the liquid can be accounted for by a simple scattering model. (c) Preliminary information on band gaps in liquid rare gases were obtained from the spectroscopic data. (d) The effect of liquid-solid phase transition on the line broadening of exciton states is consistent with electron mobility data in these systems.

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