Recent Advances in Solid-State Nuclear Magnetic Resonance Techniques for Materials Research

2020 ◽  
Vol 50 (1) ◽  
pp. 493-520
Author(s):  
Po-Hsiu Chien ◽  
Kent J. Griffith ◽  
Haoyu Liu ◽  
Zhehong Gan ◽  
Yan-Yan Hu

Establishing structure–property correlations is of paramount importance to materials research. The ability to selectively detect observable magnetization from transitions between quantized spin states of nuclei makes nuclear magnetic resonance (NMR) spectroscopy a powerful probe to characterize solids at the atomic level. In this article, we review recent advances in NMR techniques in six areas: spectral resolution, sensitivity, atomic correlations, ion dynamics, materials imaging, and hardware innovation. In particular, we focus on the applications of these techniques to materials research. Specific examples are given following the general introduction of each topic and technique to illustrate how they are applied. In conclusion, we suggest future directions for advanced solid-state NMR spectroscopy and imaging in interdisciplinary research.

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ashlea Hughes ◽  
Frédéric Blanc

An overview of the recent role of solid-state Nuclear Magnetic Resonance (NMR) spectroscopy in the field of supramolecular chemistry to probe host-guest interactions is provided. Over the last few years,...


2018 ◽  
Vol 11 (1) ◽  
pp. 485-508 ◽  
Author(s):  
Sharon E. Ashbrook ◽  
John M. Griffin ◽  
Karen E. Johnston

The sensitivity of nuclear magnetic resonance (NMR) spectroscopy to the local atomic-scale environment offers great potential for the characterization of a diverse range of solid materials. Despite offering more information than its solution-state counterpart, solid-state NMR has not yet achieved a similar level of recognition, owing to the anisotropic interactions that broaden the spectral lines and hinder the extraction of structural information. Here, we describe the methods available to improve the resolution of solid-state NMR spectra and the continuing research in this area. We also highlight areas of exciting new and future development, including recent interest in combining experiment with theoretical calculations, the rise of a range of polarization transfer techniques that provide significant sensitivity enhancements, and the progress of in situ measurements. We demonstrate the detailed information available when studying dynamic and disordered solids and discuss the future applications of solid-state NMR spectroscopy across the chemical sciences.


Biochemistry ◽  
2008 ◽  
Vol 47 (15) ◽  
pp. 4369-4376 ◽  
Author(s):  
Karsten Seidel ◽  
Ovidiu C. Andronesi ◽  
Joachim Krebs ◽  
Christian Griesinger ◽  
Howard S. Young ◽  
...  

1999 ◽  
Vol 44 (4) ◽  
pp. 14550J ◽  
Author(s):  
Garry S. H. Lee ◽  
Don C. Craig ◽  
G. S. Kamali Kannangara ◽  
Michael Dawson ◽  
Costa Conn ◽  
...  

2021 ◽  
Author(s):  
Haijin Zhu ◽  
Luke Austin O'Dell

Ionic liquids, and their solid-state equivalents organic ionic plastic crystals, show many useful and tailorable properties that make them interesting for a wide range of applications including as electrolytes for...


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