Activity and Durability of a Membrane Electrode Assembly Fabricated with Supportless Pt Hollow Spheres for Polymer Electrolyte Fuel Cells

2017 ◽  
Vol 23 (5) ◽  
pp. 945-950 ◽  
Author(s):  
Takeo Kamino ◽  
Toshie Yaguchi ◽  
Takahiro Shimizu

AbstractPolymer electrolyte fuel cells hold great potential for stationary and mobile applications due to high power density and low operating temperature. However, the structural changes during electrochemical reactions are not well understood. In this article, we detail the development of the sample holder equipped with gas injectors and electric conductors and its application to a membrane electrode assembly of a polymer electrolyte fuel cell. Hydrogen and oxygen gases were simultaneously sprayed on the surfaces of the anode and cathode catalysts of the membrane electrode assembly sample, respectively, and observation of the structural changes in the catalysts were simultaneously carried out along with measurement of the generated voltages.


2018 ◽  
Vol 4 (4) ◽  
pp. 65 ◽  
Author(s):  
Vladislav Gamaleev ◽  
Kengo Kajikawa ◽  
Keigo Takeda ◽  
Mineo Hiramatsu

Recently, polymer electrolyte fuel cells (PEFCs) are attracting a lot of attention owing to their small size and relatively low working temperature (below 80 °C), which enables their usage in automobiles and household power generation. However, PEFCs have a problem with decreased output caused by corrosion of amorphous carbon, which is commonly used as a catalytic carrier. This problem could be solved by the usage of carbon nanostructures with a stronger crystal structure than amorphous carbon. In this work, nanographene supported by Pt nanoparticles was synthesized and examined for possible applications in the development of PEFCs with increased durability. Nanographene was synthesized by in-liquid plasma generated in ethanol using alternating current (AC) high voltage. A membrane electrode assembly (MEA) was constructed, where Pt nanoparticle-supported nanographene was used as the catalytic layer. Power generation characteristics of the MEA were evaluated and current density for the developed MEA was found to be approximately 240 mA/cm2. From the electrochemical evaluation, it was found that the durability of Pt nanoparticle-supported nanographene was about seven times higher than that of carbon black.


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