Amine-Ionic Liquid Blends in CO2 Capture Process for Sustainable Energy and Environment

In the present work, an experiment for CO2 capture process were performed by absorption using various aqueous solvent blends of amine and ionic liquids. The solvent blends were prepared for various compositions by mixing TetraButylAmmonium Acetate [TBA][OAC] and TetraButylAmmonium Bromide [TBA][Br] ionic liquids with Monoethanolamine (MEA). The obtained results were compared with baseline MEA. It was observed that capture efficiency of CO2, absorption rate of CO2 and CO2 diffusion coefficient of MEA-[TBA][OAC] and MEA-[TBA][Br] solvent blends were comparatively higher than baseline 30%MEA. Moreover, the parameters such as density, viscosity, pH, carbon loading and surface tension of all the solvent blends were measured for before and after absorption process. The carbon loading of solvent blends MEA-[TBA][Br] (0.405 mole of CO2/mole of solvent) and MEA-[TBA][OAC](0.459 mole of CO2/mole of solvent) was slightly lower than baseline MEA (0.494 mole of CO2/mole of solvent). However, the viscosity of MEA-[TBA][Br] blends were remarkably lower than MEA-[TBA][OAC] blend and baseline MEA. This might be an important key factor in solvent recovery process with lesser energy demand for sustainable energy and environment.