Use of Monosize Dispersions in Silver Halide Photographic Emulsions

Author(s):  
Trevor Maternaghan

In studying the mechanism of the photographic process the question naturally arises as to the part played by the silver halides, which form the basis of practically all photographic emulsions. It becomes important to determine whether, or not, the photographic mechanism can be linked up with one or more particular characteristics of these silver salts. Especially is this so in view of the fact that some investigators have developed theories in which the silver halides play no direct part in the photo-reaction taking place on exposure. They have assumed that the absorption of the active light and the resulting process occurs in other light sensitive substances associated with the silver halides in the emulsions, and that the function of the silver halide is merely to act as a source from which metallic silver is produced by the process of development. Weigert especially supports this idea at the present time. It seems to us, however, that the evidence which now exists is not only strongly against this view, but is in favour of the idea that the primary photographic process is intimately concerned with the absorption of light by the silver halides themselves, and may indeed be identified with certain of their characteristic properties.


MRS Bulletin ◽  
1996 ◽  
Vol 21 (7) ◽  
pp. 14-19 ◽  
Author(s):  
Cathy A. Fleischer ◽  
Charles L. Bauer ◽  
Dennis J. Massa ◽  
Jeffrey F. Taylor

Since its development over 150 years ago, silver-halide imaging has retained a central role in the imaging world, despite advances in electronic imaging over the last five to 10 years. At present the high cost of electronic cameras and printing systems prohibits their widespread general use. Nevertheless digital electronic features are now being incorporated into silver-halide-based imaging systems. Development of new films that incorporate magnetic-storage capability into conventional silver-halide film, as well as smaller cameras and tighter winding radii, put more stringent requirements on the physical performance of the final silver-halide-based product.For many years, advances in silver-halide imaging focused on improved photographic emulsions, providing improvements in resolution, color balance, and latitude. Advances in the photographic emulsions resulted from particle shape and morphology control of the silver-halide crystal, as well as new sensitizing dyes, couplers, and other image-modifying addenda that provided increases in speed and quality. Literature on the “science of photography” and “photographic materials and processes” emphasizes silver-halide chemistry and the function of sensitizing dyes and couplers in color photography as they impact film latitude, resolution, color balance, etc., with minor mention of the support materials and properties. Literature on support characteristics and physical properties is limited.


2009 ◽  
Vol 54 (7) ◽  
pp. 1002-1006 ◽  
Author(s):  
N. M. Ganzherli ◽  
S. N. Gulyaev ◽  
A. S. Gurin ◽  
D. D. Kramushchenko ◽  
I. A. Maurer ◽  
...  

1922 ◽  
Vol 194 (6) ◽  
pp. 828 ◽  
Author(s):  
A.P.H. Trivelli ◽  
F.L. Righter ◽  
S.E. Sheppard

2001 ◽  
Vol 73 (3) ◽  
pp. 455-458 ◽  
Author(s):  
I. R. Gould ◽  
J. R. Lenhard ◽  
A. A. Muenter ◽  
S. A. Godleski ◽  
S. Y. Farid

A new mechanism for spectral sensitization of silver halide is described, which can potentially double the sensitivity of photographic emulsions. The photooxidized sensitizing dye is trapped using an organic donor molecule, which fragments to form a cation and a reducing radical, which injects an electron into the conduction band of the silver halide. In this way, two conduction-band electrons can be produced for each absorbed photon.


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