Ethyl Vinyl Ether

1955 ◽  
Vol 34 (4) ◽  
pp. 235???240 ◽  
Author(s):  
Max S. Sadove ◽  
Gordon M. Wyant ◽  
John O. Cletcher
Heterocycles ◽  
1996 ◽  
Vol 43 (11) ◽  
pp. 2457 ◽  
Author(s):  
Takehiro Sano ◽  
Jun Toda ◽  
Toshiaki Saitoh ◽  
Taichi Oyama ◽  
Yoshie Horiguchi

Inorganics ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 121
Author(s):  
Takahashi ◽  
Shimbayashi ◽  
Fujita

The reaction of [(Cp*Ir)2(μ-dmpm)(μ-H)][OTf] (2) [Cp* = η5-C5Me5, dmpm = bis(dimethylphosphino)methane] with 2,3-dihydrofuran gives [(Cp*IrH)2(μ-dmpm){μ-(2,3-dihydrofuranyl)}][OTf] (3) in an isolated yield of 70% via the C–H bond activation at the 5-position of 2,3-dihydrofuran. Complex 3 is slowly converted into [(Cp*Ir)2(μ-dmpm)(μ-C=C(H)CH2CH2OH)][OTf] (4) quantitatively via the proton-mediated C–O bond activation. The reaction of 2 with ethyl vinyl ether gives [(Cp*Ir)2(μ-dmpm)(μ-CH=CH2)][OTf] (5) in the isolated yield of 64% via the successive activation of C–H and C–O bonds.


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