OS1605-221 Study on Evaluation Method of Fatigue Crack Growth and Stress Corrosion Cracking of Aluminum Alloys for Hydrogen Containers

2015 ◽  
Vol 2015 (0) ◽  
pp. _OS1605-22-_OS1605-22
Author(s):  
Takeshi OGAWA ◽  
Shota HASUNUMA ◽  
Toshihiko KANEZAKI ◽  
Satomi MANO ◽  
Kazuo MIYAGAWA
CORROSION ◽  
10.5006/3682 ◽  
2020 ◽  
Author(s):  
David Schrock ◽  
Allison Akman ◽  
Jenifer Locke

The interplay between stress corrosion cracking (SCC) and corrosion fatigue was investigated for AA5456-H116 to determine the source of the inverse relationship between fatigue loading (f) and fatigue crack growth rates (da/dN). Sensitization in 5xxx series aluminum alloys refers to the precipitation of β on α-Aluminum grain boundaries, which can occur in high-Mg 5xxx alloys after sufficient exposure to temperatures as low as 40 °C. Recent research has established that da/dN in sensitized 5xxx series aluminum alloys can be inversely dependent on f. The severity of the inverse relationship between da/dN and f has been attributed to sensitization level, alloy composition, and temper. In this work, the effect that K<sub>max</sub> has on corrosion fatigue da/dN was quantified using fracture mechanics-based experiments conducted at different maximum stress intensity factors (K<sub>max</sub>) but the same ΔK in 3.5 wt.% NaCl. Results suggest that the severity of the inverse relationship between da/dN and f (i.e., the slope of the da/dN versus f trend) is governed by the magnitude of K<sub>max</sub> in relation to the threshold stress intensity factor for stress corrosion cracking (K<sub>ISCC</sub>). In addition, results show that an inverse f-dependence, albeit with a lower slope, can exist even when K<sub>max</sub> is less than K<sub>ISCC</sub>; in other words, absent SCC. This low-slope corrosion fatigue behavior may have been driven by an enhanced rate of hydrogen embrittlement facilitated by the more aggressive local crack tip environment present at progressively lower loading frequencies during corrosion of highly sensitized microstructures.


Author(s):  
Takeshi Ogawa ◽  
Shota Hasunuma ◽  
Naoki Sogawa ◽  
Taiki Yoshida ◽  
Toshihiko Kanezaki ◽  
...  

Hydrogen gas container is one of the critical components for fuel cell electric vehicle (FCEV), which is expected for CO2-free personal transportation. In order to choose an appropriate material for its metal boss and liner, crack growth resistance should be evaluated for various aspects such as fatigue crack growth (FCG) and stress corrosion cracking (SCC) in salt water or humid air environments for the purpose of commercial vehicle use. In the present study, FCG tests were carried out for A6061 and A6066 alloys in laboratory air and in 3.5% NaCl solution for compact (CT) and single edge notched (SEN) specimens. Some SEN specimens were cut from machined hydrogen container made of A6066 at the neck and the shoulder locations. SCC tests were carried out for A6061, A6066 and A6351 (fine and coarse grains) alloys in 3.5% NaCl solution and in humid air for CT specimen.


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