Finite-size effects in surface-enhanced Raman scattering in noble-metal nanoparticles: a semiclassical approach

2006 ◽  
Vol 23 (6) ◽  
pp. 1369 ◽  
Author(s):  
Vitaliy N. Pustovit ◽  
Tigran V. Shahbazyan
2004 ◽  
Vol 818 ◽  
Author(s):  
Vitaliy N. Pustovit ◽  
Tigran V. Shahbazyan

AbstractWe study the role of a strong electron confinement on the surface-enhanced Raman scattering from molecules adsorbed on small noble-metal nanoparticles. We describe a novel enhancement mechanism which originates from the different effect that confining potential has on s-band and d-band electrons. We demonstrate that the interplay between finite-size and screening efects in the nanoparticle surface layer leads to an enhancement of the surface plasmon local field acting on a molecule located in a close proximity to the metal surface. Our calculations show that the additional enhancement of the Raman signal is especially strong for small nanometer-sized nanoparticles.


2004 ◽  
Vol 846 ◽  
Author(s):  
N. Pustovit ◽  
Tigran V. Shahbazyan

ABSTRACTWe study the role of a strong electron confinement on the surface-enhanced Raman scattering from molecules adsorbed on small noble-metal nanoparticles. We describe a novel enhancement mechanism which originates from the different effect that confining potential has on s-band and d-band electrons. We demonstrate that the interplay between finite-size and screening efects in the nanoparticle surface layer leads to an enhancement of the surface plasmon local field acting on a molecule located in a close proximity to the metal surface. Our calculations, based on time-dependent local density approximation, show that the additional enhancement of the Raman signal is especially strong for small nanometer-sized nanoparticles.


2008 ◽  
Vol 20 (22) ◽  
pp. 6939-6944 ◽  
Author(s):  
Chengmin Shen ◽  
Chao Hui ◽  
Tianzhong Yang ◽  
Congwen Xiao ◽  
Jifa Tian ◽  
...  

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