Potentiometric Selectivity Coefficients of Ion-Selective Electrodes Part III. Organic Ions

Potentiometric selectivity coefficients, KA,Bpot, have been collected for ionophore-based ion-selective electrodes (ISEs) for organic ions reported during 1988-1998. In addition to the actual numerical values of KA,Bpot together with the methods and conditions for their determination, response slopes, linear ranges, chemical compositions, and ionophore structures for the ISE membranes are tabulated.

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Cu(II) Ion-Selective Electrodes Based on Cu(II) Complex with Cyclized Salophen

Zeitschrift für Naturforschung B ◽

10.1515/znb-2003-0709 ◽

2003 ◽

Vol 58 (7) ◽

pp. 658-662 ◽

Cited By ~ 4

Author(s):

Manal R. Al-Saraj ◽

Salman M. Saadeh ◽

Monzir S. Abdel-Latif

Keyword(s):

Aqueous Solutions ◽

Ion Selective Electrodes ◽

Similar Response ◽

Membrane Composition ◽

Experimental Conditions ◽

Selectivity Coefficients ◽

Potentiometric Selectivity ◽

Coated Disc ◽

Coated Wire

Several versions of Cu(II) ion selective electrodes (ISE), based on cyclized N,N'-bis(salicylidene)-o-phenylenediamine (salophen) complexes with Cu(II), were fabricated for determination of Cu(II) in aqueous solutions. The response of the ISE was optimized by variation of membrane composition and evaluation of various experimental conditions. Near Nernstian slopes (~ 28-32 mV/decade) were obtained for some preparations. The linear range of the ISE ranged from 5 × 10-5 to 1 × 10-2M Cu(II). Coated-wire and coated disc ISE resulted practically in a similar response as screen printed electrodes (SPE). The potentiometric selectivity coefficients (Kij) for all electrodes were determined for Na+, NH4+, Ca2+, Mg2+, Ni2+, Pb2+, Zn2+, Cd2+, Co2+, Fe3+, Hg2+, CO32-, H2PO4-, HPO42-, SO42-, CH3COO-, Br-, I-, NO3-, and SCN-. The selectivity coefficients were in the range from 10-2 to 10-3 for all ions tested except Hg2+, I-, and to less extent Fe3+. Fabricated ISE using the Cu(II)-salophen complex are reliable and stable.

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Potentiometric selectivity coefficients of ion-selective electrodes. Part II. Inorganic anions (IUPAC Technical Report)

Pure and Applied Chemistry ◽

10.1351/pac200274060923 ◽

2002 ◽

Vol 74 (6) ◽

pp. 923-994 ◽

Cited By ~ 74

Author(s):

Yoshio Umezawa ◽

Kayoko Umezawa ◽

Philippe Bühlmann ◽

Naoko Hamada ◽

Hiroshi Aoki ◽

...

Keyword(s):

Inorganic Anions ◽

Ion Selective Electrodes ◽

Chemical Compositions ◽

Selectivity Coefficients ◽

Potentiometric Selectivity ◽

Technical Report ◽

Linear Concentration

Potentiometric selectivity coefficients, KA,Bpot have been collected for ionophore-based ion-selective electrodes (ISEs) for inorganic anions reported during 1988-1998. In addition to the actual numerical values of KA,Bpot together with the methods and conditions for their determination, response slopes, linear concentration (activity) ranges, chemical compositions, and ionophore structures for the ISE membranes are tabulated.

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Potentiometric Selectivity Coefficients of Ion-Selective Electrodes Part I. Inorganic Cations

IUPAC Standards Online ◽

10.1515/iupac.72.0052 ◽

2016 ◽

Author(s):

Yoshio Umezawa ◽

Philippe Bühlmann ◽

Kayoko Umezawa ◽

Koji Tohda ◽

Shigeru Amemiya

Keyword(s):

Ion Selective Electrodes ◽

Selectivity Coefficients ◽

Inorganic Cations ◽

Potentiometric Selectivity

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Measurement and comparison of potentiometric selectivity coefficients of urea biosensors based on ammonium ion-selective electrodes

IEEE Sensors Journal ◽

10.1109/jsen.2005.857881 ◽

2005 ◽

Vol 5 (6) ◽

pp. 1362-1368 ◽

Cited By ~ 12

Author(s):

Nien Hsuan Chou ◽

Jung Chuan Chou ◽

Tai Ping Sun ◽

Shen Kan Hsiung

Keyword(s):

Ammonium Ion ◽

Ion Selective Electrodes ◽

Selectivity Coefficients ◽

Potentiometric Selectivity

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Potentiometric Selectivity Coefficients of Ion-Selective Electrodes. Part I. Inorganic Cations (Technical Report)

Pure and Applied Chemistry ◽

10.1351/pac200072101851 ◽

2000 ◽

Vol 72 (10) ◽

pp. 1851-2082 ◽

Cited By ~ 590

Author(s):

Yoshio Umezawa ◽

Philippe Bühlmann ◽

Kayoko Umezawa ◽

Koji Tohda ◽

Shigeru Amemiya

Keyword(s):

Ion Selective Electrodes ◽

Chemical Compositions ◽

Selectivity Coefficients ◽

Inorganic Cations ◽

Potentiometric Selectivity ◽

Technical Report ◽

Linear Concentration

Potentiometric selectivity coefficients have been collected for ionophore-based ion-selective electrodes (ISEs) for inorganic cations reported from 1988-1997. In addition to numerical values of K(A,B)pot together with the methods and conditions for their determination, response slopes, linear concentration ranges, chemical compositions, and ionophores structures for the ISE membranes are tabulated.

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