Rotationskonstante und Kernquadrupolkopplungskonstante des Trimethylehlorsilans, bestimmt aus Mikrowellenspektren / Rotational Constant and Nuclear Quadrupole Coupling Constant of Trimethylchlorosilane, Determined by Microwave Spectrum

The microwave spectrum of trimethylchlorosilane has been investigated between 8 and 20 GHz. The quadrupole splitting of the K = 0 lines of the transitions J = 2 → 3 and 3 → 4 have been determined. The quadrupole coupling constant of the Cl-35 atom is determined to -34.701 MHz, and the rotational constant is determined to B0 = 2197.382 MHz.

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Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether

Journal of Molecular Spectroscopy ◽

10.1016/0022-2852(88)90161-0 ◽

1988 ◽

Vol 128 (2) ◽

pp. 444-455 ◽

Cited By ~ 12

Author(s):

Masaharu Fujitake ◽

Michiro Hayashi

Keyword(s):

Methyl Ether ◽

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole

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ChemInform Abstract: Microwave Spectrum, rs Structure, Dipole Moment, and Nuclear Quadrupole Coupling Constant Tensor of Ethyl Bromide.

ChemInform ◽

10.1002/chin.198836047 ◽

1988 ◽

Vol 19 (36) ◽

Author(s):

T. INAGUSA ◽

M. HAYASHI

Keyword(s):

Dipole Moment ◽

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Ethyl Bromide ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole

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ChemInform Abstract: Microwave Spectrum, Structure and Nuclear Quadrupole Coupling Constant Tensor of Ethyl Chloride and Vinyl Chloride

ChemInform ◽

10.1002/chin.199027059 ◽

1990 ◽

Vol 21 (27) ◽

Author(s):

M. HAYASHI ◽

T. INAGUSA

Keyword(s):

Vinyl Chloride ◽

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Ethyl Chloride ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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Microwave Spectrum, Structure, and Nuclear Quadrupole Coupling Constant Tensor of Iodomethyl Methyl Ether

Journal of Molecular Spectroscopy ◽

10.1006/jmsp.1995.1122 ◽

1995 ◽

Vol 171 (2) ◽

pp. 328-343 ◽

Cited By ~ 8

Author(s):

M. Hayashi ◽

Y. Morimoto ◽

N. Inada

Keyword(s):

Methyl Ether ◽

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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Microwave spectrum, structure, and nuclear quadrupole coupling constant tensor of isopropyl bromide and iodide

Journal of Molecular Spectroscopy ◽

10.1016/0022-2852(89)90160-4 ◽

1989 ◽

Vol 135 (2) ◽

pp. 334-348 ◽

Cited By ~ 30

Author(s):

Chikako Ikeda ◽

Toshihiro Inagusa ◽

Michiro Hayashi

Keyword(s):

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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Microwave spectrum, structure, and nuclear quadrupole coupling constant tensor of methyl iodosilane

Journal of Molecular Spectroscopy ◽

10.1016/0022-2852(89)90158-6 ◽

1989 ◽

Vol 135 (2) ◽

pp. 305-313 ◽

Cited By ~ 12

Author(s):

Michiro Hayashi ◽

Masaharu Fujitake ◽

Kenji Kishioka

Keyword(s):

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Constant Tensor ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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The microwave spectrum, structure, dipole moment, and 14N nuclear quadrupole coupling constant of acetonitrile-N-oxide

Chemical Physics Letters ◽

10.1016/0009-2614(70)80259-7 ◽

1970 ◽

Vol 7 (1) ◽

pp. 102-104 ◽

Cited By ~ 23

Author(s):

P.B. Blackburn ◽

R.D. Brown ◽

F.R. Burden ◽

J.G. Crofts ◽

I.R. Gillard

Keyword(s):

Dipole Moment ◽

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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Microwave spectrum, structure, and nuclear quadrupole coupling constant tensor of vinyl bromide and iodide

Journal of Molecular Spectroscopy ◽

10.1016/0022-2852(90)90067-z ◽

1990 ◽

Vol 139 (2) ◽

pp. 299-312 ◽

Cited By ~ 35

Author(s):

Michiro Hayashi ◽

Chikako Ikeda ◽

Toshihiro Inagusa

Keyword(s):

Quadrupole Coupling Constant ◽

Microwave Spectrum ◽

Coupling Constant ◽

Constant Tensor ◽

Vinyl Bromide ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Nuclear Quadrupole ◽

Spectrum Structure

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Nitrogen-14 Nuclear Quadrupole Coupling and Centrifugal Distortion of Pivalonitrile

Zeitschrift für Naturforschung A ◽

10.1515/zna-1986-1107 ◽

1986 ◽

Vol 41 (11) ◽

pp. 1307-1310

Author(s):

Eckhard Fliege ◽

Helmut Dreizler ◽

A. Peter Cox

Keyword(s):

Quadrupole Coupling Constant ◽

Rotational Constant ◽

Coupling Constant ◽

Centrifugal Distortion ◽

Nuclear Quadrupole Coupling Constant ◽

Quadrupole Coupling ◽

Constant E ◽

Nuclear Quadrupole ◽

Distortion Parameters ◽

Cyano Compounds

The rotational transitions J' - J" = 1 - 0 , 2 - 1 , 3 - 2 , and 4 - 3 of pivalonitrile have been measured in the frequency range of 5 - 2 2 GHz with a microwave Fourier transform spectrometer. The 14N nuclear quadrupole coupling constant, e q Q, as well as the centrifugal distortion parameters, DJ and DJK, have been determined to be: e q Q = - 4.221(15) MHz; DJ = 0.349(56) kHz, DJK = - 3.68(15) kHz. The rotational constant B0 was fixed with high precision: B0 = 2749.9093(13) MHz. Nitrogen-14 quadrupole coupling in pivalonitrile is compared with that in other cyano compounds.

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