X-ray Diffraction Study of Aqueous Solutions of ZnSO4

1982 ◽  
Vol 37 (10) ◽  
pp. 1205-1210 ◽  
Author(s):  
G. Licheri ◽  
G. Paschina ◽  
G. Piccaluga ◽  
G. Pinna

Five aqueous solutions of ZnSO4 of concentrations ranging from 0.6M to 3.1 M were examined by X-ray diffraction. In the correlation functions no concentration effect on structural phenomena is detectable. The same model was then successfuly used for all cases, attributing two hydration shells to Zn2+ and one hydration shell to SO42+ . The reliability of the structural parameters obtained is discussed.

1977 ◽  
Vol 19 (3) ◽  
pp. 371-376 ◽  
Author(s):  
R. Caminiti ◽  
G. Licheri ◽  
G. Piccaluga ◽  
G. Pinna

1997 ◽  
Vol 52 (6-7) ◽  
pp. 521-527 ◽  
Author(s):  
Toshiyuki Takamuku ◽  
Motoyuki Yamagami ◽  
Hisanobu Wakita ◽  
Toshio Yamaguchi

Abstract X-ray diffraction measurements were performed on liquid LiBr • 5H2O and Lil • 5H2O at temperatures from -30 to 25 °C. The total radial distribution functions did show that on supercooling the hydration shell of the halide ions becomes more structured, while that of the lithium ions becomes distorted. The larger the halide ion, the stronger becomes the water-water interaction around halide ions with lowering temperature. However, the distance between the water molecules in the hydration shells of the halide ions depends little on their size. On the basis of the present results, together with those of our previous investigation on LiCl • 5H2O at temperatures from - 135 to 100°C, the effects of temperature and the size of the halide ions on the structure of the solution are discussed.


1984 ◽  
Vol 81 (12) ◽  
pp. 6059-6063 ◽  
Author(s):  
G. Licheri ◽  
G. Paschina ◽  
G. Piccaluga ◽  
G. Pinna

1985 ◽  
Vol 16 (16) ◽  
Author(s):  
G. LICHERI ◽  
G. PASCHINA ◽  
G. PICCALUGA ◽  
G. PINNA

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