Remarks on Local Energy and Perturbations
Abstract The local energy is first reviewed and compared with the expected energy. We then present the perturbative local energy method which uses an exactly soluble base problem and a perturbing potential to greatly simplify the expression of the local energy. This is demonstrated with two-electron atoms for which the method gives upper bounds with errors from 18% for He to 4% for Ne8+. Finally a call to develop a local energy method for large systems is issued.
1960 ◽
Vol 32
(2)
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pp. 313-317
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1974 ◽
Vol 60
(10)
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pp. 3875-3881
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1966 ◽
Vol 45
(2)
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pp. 565-569
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2011 ◽
Vol 34
(11)
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pp. 921-943
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1988 ◽
Vol 28
(1)
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pp. 1-12
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2002 ◽
Vol 112
(5)
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pp. 2320-2320
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1971 ◽
Vol 97
(4)
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pp. 1093-1102
1963 ◽
Vol 39
(7)
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pp. 1698-1702
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