The Nephelauxetic Effect — Calculation and Accuracy of the Interelectronic Repulsion Parameters
1972 ◽
Vol 27
(1)
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pp. 1-6
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Keyword(s):
Expressions are reviewed which may be used to determine 10 Dq and B from the spin-allowed bands in the optical spectra of d3 and d7 electron systems within octahedral and tetrahedral sym metry. Application to low-temperature single crystal spectra demonstrates that (i) the semi-empirical ligand field theory reproduces transition energies with sufficient accuracy; (ii) differences in the values of 10 Dq and B observed with different fitting methods may be attributed to the inaccuracy of experimental data; (iii) there are generally valid values of B35 and β35 for each complex ion.
Keyword(s):
Keyword(s):
1983 ◽
Vol 23
(1)
◽
pp. 169-183
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Keyword(s):
2015 ◽
Vol 622
◽
pp. 120-123
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Keyword(s):
1959 ◽
Vol 31
(4)
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pp. 1050-1061
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2013 ◽
Vol 428
◽
pp. 012023
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1967 ◽
Vol 71
(10)
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pp. 3155-3165
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1976 ◽
Vol 41
(11)
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pp. 3232-3244
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